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Structural Phase Transition in (NMe4)2TCNQ3
http://hdl.handle.net/2298/10491
http://hdl.handle.net/2298/10491fe61ea83-109e-4ce5-aa48-ef286e381906
名前 / ファイル | ライセンス | アクション |
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論文[5].pdf (136.7 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2009-01-22 | |||||
タイトル | ||||||
タイトル | Structural Phase Transition in (NMe4)2TCNQ3 | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | (NMe4)2TCNQ3, Structural phase transition, X-ray diffraction | |||||
資源タイプ | ||||||
資源タイプ | journal article | |||||
著者 |
八木, 健一郎
× 八木, 健一郎× 寺内, 暉× 黒田, 規敬× 植田, 一正× 杉本, 豊成 |
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別言語の著者 |
Yagi, Kenichiro
× Yagi, Kenichiro× Terauchi, Hikaru× 黒田, 規敬× 植田, 一正× 杉本, 豊成 |
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内容記述 | ||||||
内容記述 | The structural properties of a neutral/radical 1 : 2 mixed compound, (NMe4)2TCNQ3, have been studied by the X-ray diffraction method in a temperature range between 25 and 150 ℃. The experimental data show that a second order phase transition takes place at around 60 ℃ and that the high-temperature phase has a monoclinic C2/m structure. The molecular planes of dimerized TCNQ-· radicals, being slipped against each other in the low temperature phase, are expected from the C2/m symmetry to be totally eclipsed in the high-temperature phase. A good fit of the power law (1-T/Tc)a to the temperature variation of the intensity of the Bragg reflection arising from the slipped TCNQ-· radicals is obtained with Tc = 330.7±0.8 K and a = 0.66±0.05 for T≤Tc. Influences of this novel phase transition on the electronic properties are discussed. | |||||
書誌情報 |
Journal of the Physical Society of Japan 巻 68, 号 12, p. 3770-3773, 発行年 1999-12 |
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書誌レコードID | ||||||
収録物識別子 | AA00704814 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
関連識別子 | https://doi.org/10.1143/JPSJ.68.3770 | |||||
権利 | ||||||
権利情報 | © 1999 The Physical Society of Japan | |||||
情報源(ISSN) | ||||||
関連名称 | 00319015 | |||||
フォーマット | ||||||
内容記述 | application/pdf | |||||
形態 | ||||||
136713 bytes | ||||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
日本十進分類法 | ||||||
主題 | 431 | |||||
出版者 | ||||||
出版者 | Physical Society of Japan | |||||
資源タイプ | ||||||
内容記述 | 論文(Article) | |||||
資源タイプ・ローカル | ||||||
雑誌掲載論文 | ||||||
資源タイプ・NII | ||||||
Journal Article | ||||||
資源タイプ・DCMI | ||||||
text | ||||||
資源タイプ・ローカル表示コード | ||||||
01 | ||||||
コメント | ||||||
黒田規敬: 熊本大学大学院自然科学研究科マテリアル工学講座・工学部マテリアル工学科 |