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High Sensitivity Arsenic Analyzer Based on Liquid-reagent-free Hydride Generation and Chemiluminescence Detection for On-site Water Analysis
http://hdl.handle.net/2298/22024
http://hdl.handle.net/2298/22024787193ef-fcfb-4e50-ad81-857c5c753593
名前 / ファイル | ライセンス | アクション |
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62 2011 Anal Sci SI.pdf (266.6 kB)
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62 2011 Anal Sci AsYAMAHA.pdf (3.1 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2011-10-27 | |||||
タイトル | ||||||
タイトル | High Sensitivity Arsenic Analyzer Based on Liquid-reagent-free Hydride Generation and Chemiluminescence Detection for On-site Water Analysis | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | Arsenic in drinking water, Field analysis, Chemiluminescence detection | |||||
資源タイプ | ||||||
資源タイプ | journal article | |||||
著者 |
Md., Abul Hashem
× Md., Abul Hashem× 城代, 琢磨× 大平, 慎一× Wakuda, Kazuo× 戸田, 敬 |
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別言語の著者 |
Md., Abul Hashem
× Md., Abul Hashem× 城代, 琢磨× 大平, 慎一 |
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内容記述 | ||||||
内容記述 | In this work, a portable and reliable instrument based on manual hydride generation and subsequent ozone induced chemiluminescence analysis was developed and optimized for measurement of aqueous arsenic in drinking water. The aim was to develop a system for use in the field in villages in developing countries where water treatment systems have been installed. Consequently, it is beneficial that the system could be operated without reagent solutions or purified water. Arsenic trihydride (arsine) was generated by reaction with solid acid and solid borohydride, and then introduced to a chemiluminescence cell where the arsine was mixed with ozone to generate chemiluminescence. The measurement could be repeated with the throughput of 60 times h–1, and the limit of detection was 0.4 μg L–1. The measurable arsenic concentration was up to 1 mg L–1 for 2 mL samples. The system was evaluated for analysis of natural water samples, and the obtained data agreed well with those from ICP-MS and sequential hydride generation flow analysis. We expect this small and inexpensive instrument will be used in developing countries. | |||||
書誌情報 |
Analytical Sciences 巻 27, 号 7, p. 733-738, 発行年 2011-07 |
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DOI | ||||||
関連タイプ | isIdenticalTo | |||||
関連識別子 | 10.2116/analsci.27.733 | |||||
権利 | ||||||
権利情報 | ©2011 The Japan Society for Analytical Chemistry | |||||
情報源(ISSN) | ||||||
関連名称 | 0525-1931 | |||||
フォーマット | ||||||
内容記述 | application/pdf | |||||
フォーマット | ||||||
内容記述 | application/pdf | |||||
形態 | ||||||
3096067 bytes | ||||||
形態 | ||||||
266629 bytes | ||||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
日本十進分類法 | ||||||
主題 | 519.1 | |||||
出版者(ヨミ) | ||||||
The Japan Society for Analytical Chemistry | ||||||
別言語の出版者 | ||||||
日本分析化学会 | ||||||
資源タイプ | ||||||
内容記述 | 論文(Article) | |||||
資源タイプ・ローカル | ||||||
雑誌掲載論文 | ||||||
資源タイプ・NII | ||||||
Journal Article | ||||||
資源タイプ・DCMI | ||||||
text | ||||||
資源タイプ・ローカル表示コード | ||||||
01 | ||||||
URL | ||||||
内容記述 | http://www.jstage.jst.go.jp/article/analsci/27/7/27_733/_article |