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Pressure-induced continuous phase transition of charge-density-wave state in a linear chain complex
http://hdl.handle.net/2298/9615
http://hdl.handle.net/2298/9615076f5079-affc-4acf-8151-f6566d3af61f
名前 / ファイル | ライセンス | アクション |
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PRL_068_3056.pdf (378.7 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2008-10-23 | |||||
タイトル | ||||||
タイトル | Pressure-induced continuous phase transition of charge-density-wave state in a linear chain complex | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | PtCl compound, 白金錯体, charge-density-wave, 電荷密度波, pressure-induced continuous phase transition, 圧力誘起連続相転移, Upsilon critical point, ウプシロン臨界点 | |||||
資源タイプ | ||||||
資源タイプ | journal article | |||||
著者 |
Kuroda, Noritaka
× Kuroda, Noritaka× 酒井, 政道× 仁科, 雄一郎× Sasaki, Kazuo |
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別言語の著者 |
黒田, 規敬
× 黒田, 規敬× 酒井, 政道× 仁科, 雄一郎× 佐々木, 一夫 |
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内容記述 | ||||||
内容記述 | [Pt(en)2][Pt(en)2Cl2](ClO4)4 (en=ethylenediamine) is found to undergo a novel phase transition from the charge-density-wave (CDW) state to a new phase under hydrostatic pressure. The new phase appears at 3 GPa and coexists with the CDW state up to 6 GPa, at least. The volume ratio between the two coexisting phases measured by Raman scattering spectroscopy changes continuously with pressure. The result is discussed in terms of the theoretical approach to the polymorphic phase transition developed recently by Bassler, Sasaki, and Griffiths. It is suggested that kink solitons play an important role in this phase transition. | |||||
内容記述 | ||||||
内容記述 | 擬一次元白金錯体の高圧光効果を従来よりもさらに高い圧力領域にまで拡張して測定した結果、およそ3 GPaで擬一次元結合の電荷密度波状態に、通常の圧力誘起構造相転移では理解できない、新種の相転移が生じることが見出された。この相転移の特徴は、低圧相が消失せず、6 GPa以上の圧力下でも可逆的に高圧相と共存することである。実験データの解析より、理論的にしか知られていなかった新しいタイプの臨界点(ウプシロン臨界点)がこの物質系で実現している可能性の高いことを論考した。 | |||||
書誌情報 |
Physical Review Letters 巻 68, 号 20, p. 3056-3059, 発行年 1992-05-18 |
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ISSN | ||||||
収録物識別子 | 00319007 | |||||
書誌レコードID | ||||||
収録物識別子 | AA00773679 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
関連識別子 | 10.1103/PhysRevLett.68.3056 | |||||
権利 | ||||||
権利情報 | ©1992 The American Physical Society | |||||
フォーマット | ||||||
内容記述 | application/pdf | |||||
形態 | ||||||
378673 bytes | ||||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
日本十進分類法 | ||||||
主題 | 428.4 | |||||
その他の言語のタイトル | ||||||
その他のタイトル | 直鎖錯体における電荷密度波状態の圧力誘起連続相転移 | |||||
タイトル(ヨミ) | ||||||
その他のタイトル | チョクサ サクタイ ニ オケル デンカ ミツドハ ジョウタイ ノ アツリョク ユウキ レンゾク ソウテンイ | |||||
出版者 | ||||||
出版者 | The American Physical Society | |||||
資源タイプ | ||||||
内容記述 | 論文(Article) | |||||
資源タイプ・ローカル | ||||||
雑誌掲載論文 | ||||||
資源タイプ・NII | ||||||
Journal Article | ||||||
資源タイプ・DCMI | ||||||
text | ||||||
資源タイプ・ローカル表示コード | ||||||
01 | ||||||
URL | ||||||
内容記述 | http://link.aps.org/abstract/PRL/v68/p3056 | |||||
コメント | ||||||
黒田規敬: 熊本大学大学院自然科学研究科マテリアル工学講座・工学部マテリアル工学科 |