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High-pressure infrared absorption in Cs2TCNQ3 crystals grown under magnetic field
http://hdl.handle.net/2298/10531
http://hdl.handle.net/2298/10531ae8e99bc-0676-4069-bf79-8303d7690d46
名前 / ファイル | ライセンス | アクション |
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論文[15].pdf (144.8 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2009-01-26 | |||||
タイトル | ||||||
タイトル | High-pressure infrared absorption in Cs2TCNQ3 crystals grown under magnetic field | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | Crystal growth, High magnetic field, High pressure, Optical spectroscopy, TCNQ complex | |||||
資源タイプ | ||||||
資源タイプ | journal article | |||||
著者 |
Hasanudin
× Hasanudin× Kuroda, Noritaka× 杉本, 豊成× 茂木, 巌× 渡辺, 和雄 |
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別言語の著者 |
黒田, 規敬
× 黒田, 規敬× 杉本, 豊成× 茂木, 巌× 渡辺, 和雄 |
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内容記述 | ||||||
内容記述 | Pressure dependence of infrared absorption has been measured in Cs2TCNQ3 single crystals grown under magnetic field of 5 T (5 T crystals). The behavior of the C-CN as well as C-H stretching modes suggest that there occurs a phase transition which resembles to the one related to the insulator to metal transition in the crystals grown without magnetic field (0 T crystals). This transition, however, takes place at 4.1 GPa, slightly higher than the case of 0 T crystals. The charge transfer degree of the neutral and radical molecules are found to be ρ = 0.30-0.37 and 0.81-0.85, respectively, which are significantly different from that of 0 T crystals. These differences are suggested to arise from the changes in the relative positions of the TCNQ molecules, as indicated from the behavior of the EMV mode. | |||||
書誌情報 |
Synthetic Metals 巻 148, 号 3, p. 307-312, 発行年 2005-02-10 |
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書誌レコードID | ||||||
収録物識別子 | AA00446016 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
関連識別子 | 10.1016/j.synthmet.2004.10.011 | |||||
権利 | ||||||
権利情報 | © 2004 Elsevier B.V. All rights reserved. | |||||
情報源(ISSN) | ||||||
関連名称 | 03796779 | |||||
フォーマット | ||||||
内容記述 | application/pdf | |||||
形態 | ||||||
144767 bytes | ||||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
日本十進分類法 | ||||||
主題 | 431 | |||||
出版者 | ||||||
出版者 | Elsevier BV | |||||
資源タイプ | ||||||
内容記述 | 論文(Article) | |||||
資源タイプ・ローカル | ||||||
雑誌掲載論文 | ||||||
資源タイプ・NII | ||||||
Journal Article | ||||||
資源タイプ・DCMI | ||||||
text | ||||||
資源タイプ・ローカル表示コード | ||||||
01 | ||||||
著作の一部 | ||||||
関連名称 | http://dx.doi.org/10.1016/j.synthmet.2004.10.011 | |||||
URL | ||||||
内容記述 | http://www.elsevier.com/wps/find/journaldescription.cws_home/504105/description#description | |||||
コメント | ||||||
黒田規敬: 熊本大学大学院自然科学研究科マテリアル工学講座・工学部マテリアル工学科 |