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カーボン電極上でのペルオキシダーゼの電子移動反応(<特 集>表面・界面・薄膜と分析化学)
http://hdl.handle.net/2298/20098
http://hdl.handle.net/2298/2009804c7c907-0000-4e26-9206-3e13c26da904
名前 / ファイル | ライセンス | アクション |
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110002907247.pdf (222.4 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2011-07-07 | |||||
タイトル | ||||||
タイトル | カーボン電極上でのペルオキシダーゼの電子移動反応(<特 集>表面・界面・薄膜と分析化学) | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ | journal article | |||||
著者 |
冨永, 昌人
× 冨永, 昌人× 谷口, 功 |
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別言語の著者 |
Tominaga, Masato
× Tominaga, Masato× Taniguchi, Isao |
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内容記述 | ||||||
内容記述 | Electrode reactions of horseradish peroxidase (HRP) at pyrolytic graphite (PG) electrodes were examined by cyclic voltammetry. HRP gave a redox wave around -0.3 V (vs. Ag/AgCl) at pH 8,which was due to heme of the HRP adsorbed on the electrode : HRP(Fe^<3+>)_<ad> +e→HRP(Fe^<2+>)_<ad>. The addition of H_2O_2 to the HRP solution induced a catalytic reduction current at thc electrode around -0.4 V at pH 8 ; larger catalytic currents were obtained in acidic solutions. This catalytic reduction of H_2O_2 can be given as 2HRP(Fe^<2+>)_<ad>+H_2O2+2H^+→2HRP(Fe^<3+>)_<ad>+2H_2O, where the catalytic reduction took place favorably through the reduction of heme in HRP. but not through the free heme moiety dissociated from HRP. | |||||
書誌情報 |
分析化学 巻 40, 号 11, p. 859-861, 発行年 1991-11-05 |
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書誌レコードID | ||||||
収録物識別子 | AN00222633 | |||||
権利 | ||||||
権利情報 | 社団法人日本分析化学会 | |||||
情報源(ISSN) | ||||||
関連名称 | 05251931 | |||||
フォーマット | ||||||
内容記述 | application/pdf | |||||
形態 | ||||||
222407 bytes | ||||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
日本十進分類法 | ||||||
主題 | 433 | |||||
その他の言語のタイトル | ||||||
その他のタイトル | Electron-transfer reactions of peroxidase at carbon electrodes (<Special Articles>Analytical Chemistry in Surface, Interface and Thin Film) | |||||
タイトル(ヨミ) | ||||||
その他のタイトル | カーボン デンキョクジョウ ノ ペルオキシダーゼ ノ デンシ イドウ ハンノウ : トクシュウ ヒョウメン カイメン ハクマク ト ブンセキ カガク | |||||
出版者 | ||||||
出版者 | 社団法人日本分析化学会 | |||||
資源タイプ | ||||||
内容記述 | 論文(Article) | |||||
資源タイプ・ローカル | ||||||
雑誌掲載論文 | ||||||
資源タイプ・NII | ||||||
Journal Article | ||||||
資源タイプ・DCMI | ||||||
text | ||||||
資源タイプ・ローカル表示コード | ||||||
01 | ||||||
URL | ||||||
内容記述 | http://ci.nii.ac.jp/naid/110002907247 | |||||
コメント | ||||||
本文データは学協会の許諾に基づきCiNiiから複製したものである |