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Efficient Preparation of 1,3-Diol derivatives with Three Contiguous Stereocenters by an Enantioselective Direct Aldol-Tishchenko Reaction
http://hdl.handle.net/2298/29404
http://hdl.handle.net/2298/29404ae70024d-8241-4562-99c6-5f87778daf15
名前 / ファイル | ライセンス | アクション |
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Synthesis,44,20,3145-3151.pdf (306.7 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2014-02-24 | |||||
タイトル | ||||||
タイトル | Efficient Preparation of 1,3-Diol derivatives with Three Contiguous Stereocenters by an Enantioselective Direct Aldol-Tishchenko Reaction | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | aldol reaction, asymmetric catalysis, enantioselectivity, stereoselectivity, tandem reaction | |||||
資源タイプ | ||||||
資源タイプ | journal article | |||||
著者 |
一番ヶ瀬, 友紀
× 一番ヶ瀬, 友紀× 中島, 誠 |
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別言語の著者 |
一番ヶ瀬, 友紀
× 一番ヶ瀬, 友紀× 中島, 誠 |
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内容記述 | ||||||
内容記述 | 1,3-Diol derivatives with three contiguous stereocenters were efficiently prepared by an enantioselective direct aldol–Tishchenko reaction catalyzed by dilithium 3,3’-diphenylbinaphtholate. The reactions of acyclic ketones as aldol donors gave 1,2-syn-1,3-anti diol derivatives, whereas the reactions of cyclic ketones as aldol donors gave 1,2-anti-1,3-anti diol derivatives. Sequential aldol–aldol–Tishchenko reactions gave a triol derivative with five consecutive chiral centers. | |||||
書誌情報 |
Synthesis 巻 44, 号 20, p. 3145-3151, 発行年 2012-10 |
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ISSN | ||||||
収録物識別子 | 0039-7881 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
関連識別子 | 10.1055/s-0031-1291138 | |||||
権利 | ||||||
権利情報 | © 2012 Georg Thieme Verlag | |||||
フォーマット | ||||||
内容記述 | application/pdf | |||||
形態 | ||||||
306691 bytes | ||||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
日本十進分類法 | ||||||
主題 | 499 | |||||
出版者 | ||||||
出版者 | Georg Thieme Verlag | |||||
資源タイプ | ||||||
内容記述 | 論文(Article) | |||||
資源タイプ・ローカル | ||||||
雑誌掲載論文 | ||||||
資源タイプ・NII | ||||||
Journal Article | ||||||
資源タイプ・DCMI | ||||||
text | ||||||
資源タイプ・ローカル表示コード | ||||||
01 | ||||||
URL | ||||||
内容記述 | https://www.thieme-connect.de/DOI/DOI?10.1055/s-0031-1291138 |