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Viscosity and Fragility of Polymer Electrolytes based on PPO and PPG
http://hdl.handle.net/2298/26163
http://hdl.handle.net/2298/2616383c6574d-64f0-4d85-8a4e-d9ef95d3d39c
名前 / ファイル | ライセンス | アクション |
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PR0014_021-026.pdf (218.8 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2012-12-20 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Viscosity and Fragility of Polymer Electrolytes based on PPO and PPG | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ | departmental bulletin paper | |||||
著者 |
Sahara
× Sahara× Aniya, Masaru |
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内容記述 | ||||||
内容記述 | The Bond Strength-Coordination Number Fluctuation (BSCNF) model and the Williams-Landel-Ferry (WLF) equation have been used to study the temperature dependence of the viscosity of polymer electrolytes NaCF3SO3 - PPO (4000), NaCF3SO3 - PPG (4000) and LiClO4 - PPG (4000). The result indicates that both models describe well the temperature dependence of the viscosity reported experimentally. The analysis based on the BSCNF model suggests that by increasing the salt content, the fragility index increases due to the decrease of the connectivity between the structural units. The result indicates also that the empirical parameters used in the WLF equation could be related with the parameters of the BSCNF model. | |||||
書誌情報 |
en : Physics Reports of Kumamoto University 巻 14, 号 1, p. 21-26, 発行年 2012 |
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ISSN | ||||||
収録物識別子 | 0303-4070 | |||||
NCID | ||||||
収録物識別子 | AA00774081 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
日本十進分類法 | ||||||
主題 | 431.7 | |||||
出版者 | ||||||
言語 | ja | |||||
出版者 | 熊本大学 |