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Mn(III)-based reaction of alkenes with quinolinones. Formation of peroxyquinolinones and quinoline-related derivatives
http://hdl.handle.net/2298/29561
http://hdl.handle.net/2298/295613214d462-5356-4860-bf01-13465dcc5ec8
名前 / ファイル | ライセンス | アクション |
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Tet-NKHY-repository.pdf (26.2 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2014-03-11 | |||||
タイトル | ||||||
タイトル | Mn(III)-based reaction of alkenes with quinolinones. Formation of peroxyquinolinones and quinoline-related derivatives | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | Hydroperoxides, Endoperoxides, Quinolines, Propellanes, Aerobic oxidation, Mn(III), Oxidation | |||||
資源タイプ | ||||||
資源タイプ | journal article | |||||
著者 |
Nishino, Hiroshi
× Nishino, Hiroshi× 隈部, 了浩× 浜田, 諒一× ヤクト, メタプ |
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別言語の著者 |
西野, 宏
× 西野, 宏× 隈部, 了浩× 浜田, 諒一 |
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内容記述 | ||||||
内容記述 | The reactions of 1,1-disubstituted alkenes with 4-hydroxyquinolin-2(1H)-ones under both Mn(III)-catalyzed aerobic oxidation conditions at room temperature and Mn(III)-mediated oxidation conditions at reflux temperature are described. The Mn(III)-catalyzed aerobic oxidation afforded bis(hydroperoxyethyl)quinolinones and azatrioxa[4.4.3]propellanes, while the oxidation with Mn(OAc)3•2H2O produced furo[3,2-c]quinolin-4-one analogues. The existence of a substituent at the 3-position of the 4-hydroxyquinolin-2(1H)-ones prevented a double reaction with the alkenes, and (endoperoxy)quinolinones and/or (hydroperoxyethyl)quinolinones were obtained under the Mn(III)-catalyzed aerobic conditions, while furo[3,2-c]quinolinone hemiacetals and vinylquinolinones were selectively produced under the Mn(III)-mediated oxidation conditions depending on the reaction temperature and times. Cyclic assembly of quinolinone-related 1,3-dicarbonyl compounds such as dihydropyridinones, pyranones, and dimedone derivatives was also examined under elevated temperature conditions. | |||||
書誌情報 |
Tetrahedron 巻 70, 号 7, p. 1437-1450, 発行年 2014-02-18 |
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DOI | ||||||
関連タイプ | isVersionOf | |||||
関連識別子 | 10.1016/j.tet.2014.01.013 | |||||
権利 | ||||||
権利情報 | © Elsevier Limited | |||||
フォーマット | ||||||
内容記述 | application/pdf | |||||
形態 | ||||||
26249919 bytes | ||||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
日本十進分類法 | ||||||
主題 | 436 | |||||
出版者 | ||||||
出版者 | Elsevier Limited | |||||
資源タイプ | ||||||
内容記述 | 論文(Article) | |||||
資源タイプ・ローカル | ||||||
雑誌掲載論文 | ||||||
資源タイプ・NII | ||||||
Journal Article | ||||||
資源タイプ・DCMI | ||||||
text | ||||||
資源タイプ・ローカル表示コード | ||||||
01 | ||||||
URL | ||||||
内容記述 | http://www.sciencedirect.com/science/article/pii/S0040402014000295 |