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Mn(III)‐Based Oxidative Cyclization of Alkenes Using Tricarbonyl System
http://hdl.handle.net/2298/43170
http://hdl.handle.net/2298/4317002b7655e-341b-4b09-8c2e-10d09b98b812
名前 / ファイル | ライセンス | アクション |
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slct.201801443R1_re-Revised_manuscript.pdf (418.0 kB)
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Item type | 一般雑誌記事 / Article(1) | |||||
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公開日 | 2020-02-12 | |||||
タイトル | ||||||
タイトル | Mn(III)‐Based Oxidative Cyclization of Alkenes Using Tricarbonyl System | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | 2-Acetyl-4-aryl-4-oxobutanoates, 3-Acetyl-1-arylpentane-1,4-diones, 2-(2-Aryl-2-oxoethyl)malonates, Dihydro-2H-pyrans, 5-endo-trig, 6-endo-trig, Manganese(III) acetate, Oxidative cyclization, Tandem cyclization, 2,3,3a,6a-Tetrahydrofuro[2,3-b]furans | |||||
資源タイプ | ||||||
資源タイプ | article | |||||
著者 |
Huynh, Thanh-Truc
× Huynh, Thanh-Truc× Yamakawa, Hiroyasu× Nguyen, Van-Ha× 西野, 宏 |
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別言語の著者 |
西野, 宏
× 西野, 宏 |
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内容記述 | ||||||
内容記述 | The Mn(III)-based oxidation of 1,1-disubstituted ethenes with 2-(2-aryl-2-oxoethyl)malonates, 2-acetyl-4-aryl-4-oxobutanoates, and 3-acetyl-1-arylpentane-1,4-diones was evaluated. The reaction using the malonates mainly gave the 2,3-dihydro-4H-pyran-4,4-dicarboxylates along with γ-lactones. A similar reaction using the acetyloxobutanoates and acetylpentanediones produced the 2,3,3a,6a-tetrahydrofuro[2,3-b]furans and the corresponding dihydropyrans. The cyclization was strongly affected by the nucleophilicity of the carbonyl oxygen in the carbocation intermediate, and the kinetic and thermodynamic controls of the following reaction. The structure determination and the mechanisms are discussed. | |||||
書誌情報 |
ChemistrySelect 巻 3, 号 23, p. 6414-6420, 発行日 2018-06-19 |
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ISSN | ||||||
収録物識別子 | 23656549 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
関連識別子 | 10.1002/slct.201801443 | |||||
権利 | ||||||
権利情報 | © 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim | |||||
フォーマット | ||||||
内容記述 | application/pdf | |||||
形態 | ||||||
418040 bytes | ||||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
日本十進分類法 | ||||||
主題 | 438 | |||||
出版者 | ||||||
出版者 | Wiley‐VCH | |||||
資源タイプ | ||||||
内容記述 | 論文 | |||||
資源タイプ・ローカル | ||||||
雑誌掲載論文 | ||||||
資源タイプ・NII | ||||||
Article | ||||||
資源タイプ・DCMI | ||||||
text | ||||||
資源タイプ・ローカル表示コード | ||||||
01 | ||||||
URL | ||||||
内容記述 | https://onlinelibrary.wiley.com/doi/abs/10.1002/slct.201801443 | |||||
コメント | ||||||
This is the peer reviewed version of the following article: [https://onlinelibrary.wiley.com/toc/23656549/3/23], which has been published in final form at [https://doi.org/10.1002/slct.201801443]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. |