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Rapid energy transfer and its temperature dependence in π-conjugated dendrimers
http://hdl.handle.net/2298/10291
http://hdl.handle.net/2298/10291cb13c5f8-1ab8-4638-9dfd-39cf912577a6
名前 / ファイル | ライセンス | アクション |
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pdfファイル (165.2 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2008-12-24 | |||||
タイトル | ||||||
タイトル | Rapid energy transfer and its temperature dependence in π-conjugated dendrimers | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | dendrimer, energy transfer, light-harvesting, ultrafast | |||||
資源タイプ | ||||||
資源タイプ | journal article | |||||
著者 |
赤井, 一郎
× 赤井, 一郎× Miyanari, K.× Shimamoto, T.× Fujii, A.× Nakao, H.× Okada, A.× Kanemoto, K.× Karasawa, T.× Ishida, A.× Yamada, A.× Katayama, I.× Takeda, J.× Kimura, M. |
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別言語の著者 |
赤井, 一郎
× 赤井, 一郎 |
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内容記述 | ||||||
内容記述 | We investigate a rapid energy transfer (ET) process and its temperature dependence in a star-shaped stilbenoid phthalocyanine (SSS1Pc) dendrimer having π-conjugated light-harvesting (LH) antennas. In SSS1Pc, intense corephotoluminescence is observed under selective excitation on the LH-antenna as a result of the highly efficient ET from the LH-antenna. Pump-probe experiments show that ET occurs rapidly with a rising time constant (∼ 250 fs). To understand such rapid ET, we employ a simplified ET model through a π-conjugated network between the LHantenna and the core that takes into account the steric hindrance between the LH-antenna subunits. Our model reveals that the highly efficient ET at room temperature in SSS1Pc takes place through the π-conjugated network mediated by a thermally activated torsional vibration of the aromatic ring subgroup in the LH-antenna. | |||||
書誌情報 |
Physica status solidi. C 巻 6, 号 1, p. 77-80, 発行年 2009-01 |
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書誌レコードID | ||||||
収録物識別子 | AA11896717 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
関連識別子 | 10.1002/pssc.200879803 | |||||
権利 | ||||||
権利情報 | © 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | |||||
情報源(ISSN) | ||||||
関連名称 | 16101634 | |||||
フォーマット | ||||||
内容記述 | application/pdf | |||||
形態 | ||||||
165201 bytes | ||||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
日本十進分類法 | ||||||
主題 | 420 | |||||
出版者 | ||||||
出版者 | WILEY-VCH | |||||
資源タイプ | ||||||
内容記述 | 論文(Article) | |||||
資源タイプ・ローカル | ||||||
雑誌掲載論文 | ||||||
資源タイプ・NII | ||||||
Journal Article | ||||||
資源タイプ・DCMI | ||||||
text | ||||||
資源タイプ・ローカル表示コード | ||||||
01 |