@article{oai:kumadai.repo.nii.ac.jp:00017230, author = {松本, 正裕 and Matsumoto, Masahiro and Okuno, Yoshinori and Ogata, Yukiko and Kurosaki, Hiromasa and Okamoto, Yoshinari and Otsuka, Masami}, issue = {1}, journal = {Heterocycles}, month = {Oct}, note = {application/pdf, A novel metal-chelating system comprising a 4-dimethylamino- pyridine and two histidine appendages was synthesized. The two histidines were introduced by different manners; one through an amide linkage and other via a secondary amino linkage. ESR spectrum suggested a distorted pentacoordinate configuration of the copper complex of the ligand. The iron complex of the ligand had oxygen-activating property as shown by ESR spin trapping and DNA-cleaving activity as evaluated by experiments using pUC19 DNA.}, pages = {311--318}, title = {Synthesis, oxygen activation, and DNA-cleaving property of a histidine-pyridine-histidine ligand}, volume = {69}, year = {2006}, yomi = {マツモト, マサヒロ} }