{"created":"2023-11-14T05:59:03.290530+00:00","id":2000048,"links":{},"metadata":{"_buckets":{"deposit":"97a23c27-0c96-404e-b2fc-2b46b4136406"},"_deposit":{"created_by":12,"id":"2000048","owner":"12","owners":[12],"pid":{"revision_id":0,"type":"depid","value":"2000048"},"status":"published"},"_oai":{"id":"oai:kumadai.repo.nii.ac.jp:02000048","sets":["415:416"]},"author_link":[],"control_number":"2000048","item_16_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2023-07-29","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"997","bibliographicPageStart":"992","bibliographicVolumeNumber":"77","bibliographic_titles":[{"bibliographic_title":"Journal of Natural Medicines","bibliographic_titleLang":"en"}]}]},"item_16_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"A new monoacylglyceryltrimethylhomoserine, 21F121-A (1), was isolated from the culture of Penicillium glaucoroseum (21F00121) by LCMS-guided purification. The structure was elucidated by NMR and mass spectrometries. The absolute configuration of the homoserine moiety was analyzed by the ECD spectrum after acid hydrolysis, and the S-configuration of the glycerol moiety was determined based on the spectrum of the 1,2-dibenzoyl derivative after acid hydrolysis. Although a variety of diacylglyceryltrimethylhomoserine is distributed in lower plants and fungi, a limited number of studies on monoacyl derivatives have been reported. This is the fourth sample of monoacylglyceryltrimethylhomoserine discovered from a natural source, and the second sample isolated from a fungus. Compound 1 contains an unusual branched pentaene chain attached at the sn-1 position of glycerol and weakly inhibited the growth of HCT116 cells.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_16_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Springer Nature","subitem_publisher_language":"en"}]},"item_16_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1007/s11418-023-01735-5","subitem_relation_type_select":"DOI"}}]},"item_16_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"(C) 2023, The Author(s) under exclusive licence to The Japanese Society of Pharmacognosy","subitem_rights_language":"en"}]},"item_16_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1340-3443","subitem_source_identifier_type":"PISSN"}]},"item_16_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ichiro, Kimura","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Yuki, Hitora","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Yusaku, Sadahiro","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Teppei, Kawahara","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Sachiko, Tsukamoto","creatorNameLang":"en"},{"creatorName":"塚本, 佐知子","creatorNameLang":"ja"},{"creatorName":"ツカモト, サチコ","creatorNameLang":"ja-Kana"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-11-14"}],"filename":"s11418-023-01735-5.pdf","filesize":[{"value":"1 MB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"url":"https://kumadai.repo.nii.ac.jp/record/2000048/files/s11418-023-01735-5.pdf"},"version_id":"f8d9306d-3cd2-45e9-a39c-10c421ba5042"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Penicillium glaucoroseum","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Monoacylglyceryltrimethylhomoserine","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"LCMS-guided purification","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Structure determination","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"A monoacylglyceryltrimethylhomoserine, 21F121-A, containing a branched acyl group from Penicillium glaucoroseum","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"A monoacylglyceryltrimethylhomoserine, 21F121-A, containing a branched acyl group from Penicillium glaucoroseum","subitem_title_language":"en"}]},"item_type_id":"16","owner":"12","path":["416"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-11-14"},"publish_date":"2023-11-14","publish_status":"0","recid":"2000048","relation_version_is_last":true,"title":["A monoacylglyceryltrimethylhomoserine, 21F121-A, containing a branched acyl group from Penicillium glaucoroseum"],"weko_creator_id":"12","weko_shared_id":-1},"updated":"2023-11-20T00:18:45.219426+00:00"}