| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2024-03-06 |
| タイトル |
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|
タイトル |
Selective synthesis of spiro and dispiro compounds using Mn(III)-based oxidation of tetracarbonyl compounds |
|
言語 |
en |
| 言語 |
|
|
言語 |
eng |
| キーワード |
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|
主題 |
Spiro dihydrofurans, dispiro cyclopropanes, methylenebis(cyclohexanedione)s, methylenebis(piperidinedione)s, pyranodipyridinediones, manganese(III) oxidation, oxidative cyclization |
| 資源タイプ |
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|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 著者 |
Suzuka, Yokote
Satomi, Nishikawa
Keisuke, Shibuya
Kazuki, Hisano
Hiroshi, Nishino
|
| 内容記述 |
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内容記述タイプ |
Abstract |
|
内容記述 |
The Mn(III)-based oxidation of methylenebis(cyclohexanedione)s and methylenebis(piperidinedione)s as a tetracarbonyl compound was investigated under various conditions, selectively producing spiro dihydrofurans and dispiro cyclopropanes depending on the solvent. The mechanism for the formation of the spiro dihydrofurans and dispiro cyclopropanes was discussed. In addition, a simple synthesis of a new type of alkaloid, 3,4,6,7,8,10-hexahydro-1H-pyrano[3,2-c:5,6-c']dipyridine-1,9(2H)-diones, was demonstrated. |
| 書誌情報 |
en : Tetrahedron
巻 76,
号 20,
p. 131165,
発行年 2020-05-15
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| ISSN |
|
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収録物識別子 |
0040-4020 |
| DOI |
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関連タイプ |
isVersionOf |
|
|
関連識別子 |
https://doi.org/10.1016/j.tet.2020.131165 |
| 権利 |
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権利情報 |
(C) 2020 Elsevier Ltd. All rights reserved.This manuscript version is made available under the CC-BY-NC-ND 4.0 License.http://creativecommons.org/licenses/by-nc-nd/4.0/.This is the accepted manuscript version. The formal published version is available at https://doi.org/10.1016/j.tet.2020.131165 |
| 著者版フラグ |
|
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出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 出版者 |
|
|
出版者 |
Elsevier |
Tetrahedron 2020, 76 (20), 131165.pdf
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