| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2024-03-06 |
| タイトル |
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|
タイトル |
Mn(III)-catalyzed aerobic oxidation of 2-alkenyl-1,3-diketone enols. Synthesis of 1,2-dioxin-3-ols and natural phytohormone G factors |
|
言語 |
en |
| 言語 |
|
|
言語 |
eng |
| キーワード |
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主題 |
1,2-Dioxin-3-ols, Vinyl-1,3-diketones, Natural phytohormones, Mn(III)-catalyzed aerobic oxidation, Endoperoxides, Cyclization |
| 資源タイプ |
|
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
| 著者 |
Sousuke, Oka
Shintaro, Hashimoto
Kazuki, Hisano
Hiroshi, Nishino
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| 内容記述 |
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内容記述タイプ |
Abstract |
|
内容記述 |
The Mn(III)-catalyzed aerobic oxidation of 2-vinyl-1,3-diketone enols is described. The reaction gave unsaturated endoperoxides, 1,2-dioxin-3-ols, via resonated vinyldiketone radicals. The convenient and eco-friendly reaction was applied to the synthesis of natural phytohormone G3 and the analogs. In addition, the 1,2-dioxin-3-ols were easily transformed into the corresponding acetals. |
| 書誌情報 |
en : Tetrahedron
巻 106-107,
p. 132631,
発行年 2022-01
|
| ISSN |
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収録物識別子 |
0040-4020 |
| DOI |
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関連タイプ |
isVersionOf |
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関連識別子 |
https://doi.org/10.1016/j.tet.2022.132631 |
| 権利 |
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権利情報 |
(C) 2022 Elsevier Ltd. All rights reserved.This manuscript version is made available under the CC-BY-NC-ND 4.0 License.http://creativecommons.org/licenses/by-nc-nd/4.0/.This is the accepted manuscript version. The formal published version is available at https://doi.org/10.1016/j.tet.2022.132631 |
| 著者版フラグ |
|
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出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 出版者 |
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出版者 |
Elsevier |
Tetrahedron 2022, 106-107(1,2), 132631.pdf
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