| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2024-03-06 |
| タイトル |
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|
タイトル |
Rearrangement of Methylenebis(cyclohexane-1,3-dione) Enols Induced by Mn(III)-Catalyzed Aerobic Oxidation |
|
言語 |
en |
| 言語 |
|
|
言語 |
eng |
| 資源タイプ |
|
|
資源タイプ |
journal article |
| 著者 |
Yuki Murakami
Kazuki Hisano
Hiroshi, Nishino
|
| 内容記述 |
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|
内容記述 |
The Mn(III)-catalyzed aerobic oxidation of methylenebis(cyclohexane-1,3-dione) enols 1 resulted in 6a-hydroxy-2,3,4,6a,7,8,9,10a-octahydro-1H-benzo[c]chromene-1,6,10-triones 3 during the formation of the 4,5,8,10,11,12-hexahydro-2H-benzo[b]oxecine-2,6,7,9(3H)-tetraones 2. The mechanism for the formation of 3 was proposed by the isolation of the intermediates 2 which were transformed into 3 under Claisen/retro-Claisen conditions. |
| 書誌情報 |
en : The Journal of Organic Chemistry
巻 87,
号 13,
p. 8782-8787,
発行年 2022-06-21
|
| ISSN |
|
|
収録物識別子 |
0022-3263 |
| DOI |
|
|
関連タイプ |
isVersionOf |
|
|
関連識別子 |
https://doi.org/10.1021/acs.joc.2c00647 |
| 権利 |
|
|
権利情報 |
This document is the Accepted Manuscript version of a Published Work that appeared in final form in The Journal of Organic Chemistry, copyright (C) AmericanChemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.joc.2c00647 |
| 著者版フラグ |
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|
出版タイプ |
AM |
| 出版者 |
|
|
出版者 |
American Chemical Society |
|
言語 |
en |
J. Org. Chem. 2022, 87 (13), 8782-8787.pdf
