@article{oai:kumadai.repo.nii.ac.jp:00021580, author = {Akai, Ichiro and 赤井, 一郎 and Akai, Ichiro and 赤井, 一郎 and Miyanari, K. and Shimamoto, T. and Fujii, A. and Nakao, H. and Okada, A. and Kanemoto, K. and Karasawa, T. and Ishida, A. and Yamada, A. and Katayama, I. and Takeda, J. and Kimura, M.}, issue = {1}, journal = {Physica status solidi. C}, month = {Jan}, note = {application/pdf, 論文(Article), We investigate a rapid energy transfer (ET) process and its temperature dependence in a star-shaped stilbenoid phthalocyanine (SSS1Pc) dendrimer having π-conjugated light-harvesting (LH) antennas. In SSS1Pc, intense corephotoluminescence is observed under selective excitation on the LH-antenna as a result of the highly efficient ET from the LH-antenna. Pump-probe experiments show that ET occurs rapidly with a rising time constant (∼ 250 fs). To understand such rapid ET, we employ a simplified ET model through a π-conjugated network between the LHantenna and the core that takes into account the steric hindrance between the LH-antenna subunits. Our model reveals that the highly efficient ET at room temperature in SSS1Pc takes place through the π-conjugated network mediated by a thermally activated torsional vibration of the aromatic ring subgroup in the LH-antenna.}, pages = {77--80}, title = {Rapid energy transfer and its temperature dependence in π-conjugated dendrimers}, volume = {6}, year = {2009}, yomi = {アカイ, イチロウ and アカイ, イチロウ} }