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light-harvesting (LH) antenna. Following the excitation of the LH-antennae, backbone-polymers in GnPPV give rise to intense photoluminescence (PL) bands. This is due to the presence of highly efficient energy transfer from the LH-antennae to the backbone-polymers. The intensity of backbone-PL increases faster than the decay of the antenna-PL. This result indicates that rapid energy-transfer from antenna to backbone takes place utilizing the overlap of wavefunctions in the excited states. In G2PPV having larger LH-antenna, shielding effect against inter-backbone interactions is recognized more effectively than G1PPV. In solid films of GnPPV, red shifts of the backbone-PL bands are observed. This is caused by inter-backbone interactions of the wire-type dendrimers due to aggregation. The extent of the red shift in G2PPV is smaller than that of G1PPV. This result suggests that the larger LH-antenna in G2PPV substantially wraps its backbone-polymer and shields the inter-backbone interactions.","subitem_description_type":"Other"}]},"item_16_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier Science B.V."}]},"item_16_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.jlumin.2007.11.036","subitem_relation_type_select":"DOI"}}]},"item_16_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 2007 Elsevier B.V. All rights reserved"}]},"item_16_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00701292","subitem_source_identifier_type":"NCID"}]},"item_16_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"500","subitem_subject_scheme":"NDC"}]},"item_16_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"158693 bytes"}]},"item_16_text_47":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"雑誌掲載論文"}]},"item_16_text_48":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Journal 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transfe","subitem_subject_scheme":"Other"},{"subitem_subject":"Poly-p-phenylenevinylene","subitem_subject_scheme":"Other"},{"subitem_subject":"Oligophenylene","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Energy transfer dynamics in wire-type dendrimers having oligophenylene peripheries","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Energy transfer dynamics in wire-type dendrimers having oligophenylene peripheries"}]},"item_type_id":"16","owner":"1","path":["447"],"pubdate":{"attribute_name":"公開日","attribute_value":"2008-07-25"},"publish_date":"2008-07-25","publish_status":"0","recid":"21581","relation_version_is_last":true,"title":["Energy transfer dynamics in wire-type dendrimers having oligophenylene peripheries"],"weko_creator_id":"1","weko_shared_id":1},"updated":"2023-09-12T02:38:07.753154+00:00"}