{"created":"2023-06-19T09:10:14.524859+00:00","id":21734,"links":{},"metadata":{"_buckets":{"deposit":"697962bf-4bfc-46f4-9fbb-1c40c63806e3"},"_deposit":{"created_by":1,"id":"21734","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"21734"},"status":"published"},"_oai":{"id":"oai:kumadai.repo.nii.ac.jp:00021734","sets":["426:428"]},"author_link":["93994","93988","93995","93989","146961","93996"],"item_16_alternative_title_22":{"attribute_name":"その他の言語のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"MX鎖錯体のギャップ内吸収の温度依存性における量子揺らぎの役割"}]},"item_16_alternative_title_23":{"attribute_name":"タイトル（ヨミ）","attribute_value_mlt":[{"subitem_alternative_title":"MXサ サクタイ ノ ギャップ ナイ キュウシュウ ノ オンド イゾンセイ ニ オケル リョウシ ユラギ ノ ヤクワリ"}]},"item_16_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1994-09-15","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"11","bibliographicPageEnd":"8066","bibliographicPageStart":"8063","bibliographicVolumeNumber":"50","bibliographic_titles":[{"bibliographic_title":"Physical Review B"}]}]},"item_16_creator_3":{"attribute_name":"別言語の著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"黒田, 規敬"}],"nameIdentifiers":[{"nameIdentifier":"93994","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"伊藤, 幹"}],"nameIdentifiers":[{"nameIdentifier":"93995","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"山下, 正廣"}],"nameIdentifiers":[{"nameIdentifier":"93996","nameIdentifierScheme":"WEKO"}]}]},"item_16_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_16_description_46":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"論文(Article)","subitem_description_type":"Other"}]},"item_16_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"We study the temperature dependence of persistent near-infrared absorption bands induced in single crystals of [Pt(en)2][Pt(en)2Cl2](ClO4)4, where en=ethylenediamine, by irradiation with 488-nm light. If the temperature is changed between 10 and 200 K in dark after irradiation, these bands show significant changes in the spectral position, line shape, and intensity. The behaviors of the mean energy and second and third moments of the A band are interpreted consistently in terms of a quantum-fluctuation model of solitons bound by shallow, periodic potential wells.","subitem_description_type":"Other"},{"subitem_description":"MX鎖錯体[Pt(en)2][Pt(en)2Cl2](ClO4)4に光誘起されたギャップ内吸収帯について10 Kから200 Kの範囲で温度依存性を測定し、Aバンドの光子エネルギーと2次および3次モーメントの振舞いを精密に調査した。これより、光照射で誘起されたソリトンは低温で周期ポテンシャルに束縛されて量子揺らぎ運動をしており、100-150 K以上の温度で束縛から開放されて擬1次元Pt-Cl結合の上で熱拡散運動に移行する様子が観測された。配位座標モデルによる定量解析により、ソリトンの有効質量、ソリトンに対する周期ポテンシャル、量子揺らぎの固有振動数などが求められた。","subitem_description_type":"Other"}]},"item_16_description_77":{"attribute_name":"URL","attribute_value_mlt":[{"subitem_description":"http://link.aps.org/abstract/PRB/v50/p8063","subitem_description_type":"Other"}]},"item_16_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The American Physical Society"}]},"item_16_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1103/PhysRevB.50.8063","subitem_relation_type_select":"DOI"}}]},"item_16_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"©1994 The American Physical Society"}]},"item_16_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"01631829","subitem_source_identifier_type":"ISSN"}]},"item_16_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00362255","subitem_source_identifier_type":"NCID"}]},"item_16_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"428","subitem_subject_scheme":"NDC"}]},"item_16_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"425373 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Motoki"}],"nameIdentifiers":[{"nameIdentifier":"93989","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"山下, 正弘","creatorNameLang":"ja"},{"creatorName":"ヤマシタ, マサヒロ","creatorNameLang":"ja-Kana"},{"creatorName":"Yamashita, Masahiro","creatorNameLang":"en"}],"familyNames":[{"familyName":"山下","familyNameLang":"ja"},{"familyName":"ヤマシタ","familyNameLang":"ja-Kana"},{"familyName":"Yamashita","familyNameLang":"en"}],"givenNames":[{"givenName":"正弘","givenNameLang":"ja"},{"givenName":"マサヒロ","givenNameLang":"ja-Kana"},{"givenName":"Masahiro","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"146961","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-02"}],"displaytype":"detail","filename":"PRB_050_8063.pdf","filesize":[{"value":"425.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"PRB_050_8063.pdf","url":"https://kumadai.repo.nii.ac.jp/record/21734/files/PRB_050_8063.pdf"},"version_id":"2d51476e-d8c7-42e5-8cf4-2b78ebb7511c"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"M-X chain complex","subitem_subject_scheme":"Other"},{"subitem_subject":"MX鎖錯体","subitem_subject_scheme":"Other"},{"subitem_subject":"photoinduced intragap states","subitem_subject_scheme":"Other"},{"subitem_subject":"光誘起ギャップ内状態","subitem_subject_scheme":"Other"},{"subitem_subject":"soliton","subitem_subject_scheme":"Other"},{"subitem_subject":"ソリトン","subitem_subject_scheme":"Other"},{"subitem_subject":"quantum fluctuations","subitem_subject_scheme":"Other"},{"subitem_subject":"量子揺らぎ","subitem_subject_scheme":"Other"},{"subitem_subject":"periodic potential well","subitem_subject_scheme":"Other"},{"subitem_subject":"周期ポテンシャル井戸","subitem_subject_scheme":"Other"},{"subitem_subject":"configuration coordinate model","subitem_subject_scheme":"Other"},{"subitem_subject":"配位座標モデル","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Role of quantum fluctuations in the temperature dependence of intragap absorption in an MX chain complex","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Role of quantum fluctuations in the temperature dependence of intragap absorption in an MX chain complex"}]},"item_type_id":"16","owner":"1","path":["428"],"pubdate":{"attribute_name":"公開日","attribute_value":"2008-10-23"},"publish_date":"2008-10-23","publish_status":"0","recid":"21734","relation_version_is_last":true,"title":["Role of quantum fluctuations in the temperature dependence of intragap absorption in an MX chain complex"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-10-02T07:21:31.607080+00:00"}