{"created":"2023-06-19T09:10:28.443565+00:00","id":21975,"links":{},"metadata":{"_buckets":{"deposit":"27e1f491-5b08-4f14-a1a8-e9fd20b2e9dc"},"_deposit":{"created_by":1,"id":"21975","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"21975"},"status":"published"},"_oai":{"id":"oai:kumadai.repo.nii.ac.jp:00021975","sets":["426:428"]},"author_link":["95210","95214","95212","95216","95211","95215","95217","95213"],"item_16_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2007-05-15","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"211","bibliographicPageStart":"203","bibliographicVolumeNumber":"603","bibliographic_titles":[{"bibliographic_title":"Journal of Electroanalytical Chemistry"}]}]},"item_16_creator_3":{"attribute_name":"別言語の著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"冨永, 昌人"}],"nameIdentifiers":[{"nameIdentifier":"95216","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"谷口, 功"}],"nameIdentifiers":[{"nameIdentifier":"95217","nameIdentifierScheme":"WEKO"}]}]},"item_16_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_16_description_46":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"論文(Article)","subitem_description_type":"Other"}]},"item_16_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"A nano-ordered topographical surface (0.8-1.6 nm ) was prepared by the modification of gold nano-particles on an evaporated Au film. Nano-ordered topographical effects for the protonation-deprotonation behaviors of 10-carboxy-1-decanethiol (CDT) monolayers adsorbed onto a gold surface were then demonstrated by the use of [Ru(NH3)6]3+ as a redox probe. On the assumption that current of [Ru(NH3)6]3+ on the CDT modified electrode is composed to two independent parts of the protonated and deprotonated CDT, the titration curve for the redox peak current values obtained from cyclic voltammograms of [Ru(NH3)6]3+ as a function of pH was analyzed by a statistical mechanical model for water-solid interfaces (1-pKa model). The results obtained strongly suggest that the electrostatic repulsion of the carboxylic acid terminated self-assembled monolayer adsorbed onto a gold surface with nano-ordered topography was much smaller than that adsorbed on an atomically flat gold surface, which was also supported by reflection FTIR measurements.","subitem_description_type":"Other"}]},"item_16_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier"}]},"item_16_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.jelechem.2007.01.026","subitem_relation_type_select":"DOI"}}]},"item_16_relation_16":{"attribute_name":"情報源(ISSN)","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"00220728"}]}]},"item_16_relation_53":{"attribute_name":"著作の一部","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://dx.doi.org/10.1016/j.jelechem.2007.01.026"}]}]},"item_16_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2007 Elsevier B.V."}]},"item_16_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA10836527","subitem_source_identifier_type":"NCID"}]},"item_16_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"430","subitem_subject_scheme":"NDC"}]},"item_16_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"600022 bytes"}]},"item_16_text_47":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"雑誌掲載論文"}]},"item_16_text_48":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Journal Article"}]},"item_16_text_49":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_16_text_50":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"01"}]},"item_16_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Tominaga, Masato"}],"nameIdentifiers":[{"nameIdentifier":"95210","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Maetsu, Shouko"}],"nameIdentifiers":[{"nameIdentifier":"95211","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kubo, Atsushi"}],"nameIdentifiers":[{"nameIdentifier":"95212","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Taniguchi, Isao"}],"nameIdentifiers":[{"nameIdentifier":"95213","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-02"}],"displaytype":"detail","filename":"6.pdf","filesize":[{"value":"600.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"6.pdf","url":"https://kumadai.repo.nii.ac.jp/record/21975/files/6.pdf"},"version_id":"58d2d409-85ff-46e9-9d5c-dddbee6fc481"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Carboxylic acid","subitem_subject_scheme":"Other"},{"subitem_subject":"Electrode","subitem_subject_scheme":"Other"},{"subitem_subject":"Gold nano-particles","subitem_subject_scheme":"Other"},{"subitem_subject":"Gold surface","subitem_subject_scheme":"Other"},{"subitem_subject":"Self-assembled monolayer","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Nano-ordered topographical effects on dissociation of carboxylic acid terminated self-assembled monolayers adsorbed onto a gold surface","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Nano-ordered topographical effects on dissociation of carboxylic acid terminated self-assembled monolayers adsorbed onto a gold surface"}]},"item_type_id":"16","owner":"1","path":["428"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-01-30"},"publish_date":"2009-01-30","publish_status":"0","recid":"21975","relation_version_is_last":true,"title":["Nano-ordered topographical effects on dissociation of carboxylic acid terminated self-assembled monolayers adsorbed onto a gold surface"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-06-19T19:00:47.362896+00:00"}