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The experimental data show that a second order phase transition takes place at around 60 ℃ and that the high-temperature phase has a monoclinic C2/m  structure. The molecular planes of dimerized TCNQ-· radicals, being slipped against each other in the low temperature phase, are expected from the C2/m symmetry to be totally eclipsed in the high-temperature phase. A good fit of the power law (1-T/Tc)a to the temperature variation of the intensity of the Bragg reflection arising from the slipped　TCNQ-· radicals is obtained with Tc = 330.7±0.8 K and a = 0.66±0.05 for T≤Tc. Influences of this novel phase transition on the electronic properties are discussed.","subitem_description_type":"Other"}]},"item_16_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Physical Society of Japan"}]},"item_16_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1143/JPSJ.68.3770","subitem_relation_type_select":"DOI"}}]},"item_16_relation_16":{"attribute_name":"情報源(ISSN)","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"00319015"}]}]},"item_16_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 1999 The Physical Society of 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熊本大学大学院自然科学研究科マテリアル工学講座・工学部マテリアル工学科"}]},"item_16_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"八木, 健一郎"}],"nameIdentifiers":[{"nameIdentifier":"95357","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"寺内, 暉"}],"nameIdentifiers":[{"nameIdentifier":"95358","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"Kuroda, Noritaka","creatorNameLang":"en"},{"creatorName":"黒田, 規敬","creatorNameLang":"ja"},{"creatorName":"クロダ, 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