{"created":"2023-06-19T09:10:30.236734+00:00","id":22005,"links":{},"metadata":{"_buckets":{"deposit":"29fc8304-ce55-4f17-bb9e-eff0f323a7fb"},"_deposit":{"created_by":1,"id":"22005","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"22005"},"status":"published"},"_oai":{"id":"oai:kumadai.repo.nii.ac.jp:00022005","sets":["426:428"]},"author_link":["95372","95385","95382","95383","95374","95371","95373","95384"],"item_16_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2003-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"7","bibliographicPageEnd":"1788","bibliographicPageStart":"1784","bibliographicVolumeNumber":"72","bibliographic_titles":[{"bibliographic_title":"Journal of the Physical Society of Japan"}]}]},"item_16_creator_3":{"attribute_name":"別言語の著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"黒田, 規敬"}],"nameIdentifiers":[{"nameIdentifier":"95382","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"加賀山, 朋子"}],"nameIdentifiers":[{"nameIdentifier":"95383","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"杉本, 豊成"}],"nameIdentifiers":[{"nameIdentifier":"95384","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"小林, 融弘","creatorNameLang":"ja"},{"creatorName":"コバヤシ, ミチヒロ","creatorNameLang":"ja-Kana"},{"creatorName":"Kobayashi, Michihiro","creatorNameLang":"en"}],"familyNames":[{"familyName":"小林","familyNameLang":"ja"},{"familyName":"コバヤシ","familyNameLang":"ja-Kana"},{"familyName":"Kobayashi","familyNameLang":"en"}],"givenNames":[{"givenName":"融弘","givenNameLang":"ja"},{"givenName":"ミチヒロ","givenNameLang":"ja-Kana"},{"givenName":"Michihiro","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95385","nameIdentifierScheme":"WEKO"}]}]},"item_16_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_16_description_46":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"論文(Article)","subitem_description_type":"Other"}]},"item_16_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Pressure dependence of the charge distribution along the columns of tetracyanoquinodimethane (TCNQ) molecules in Cs2TCNQ3, which is a semiconducting 1/3-filled Hubbard system with the optical energy gap of 0.3 eV at ambient conditions, has been studied by the infrared and visible absorption experiments. An electronic phase transition is found to occur at around 3.5 GPa, in accordance with the previously reported insulator-to-metal transition. Our result suggests that this phase transition accompanies a symmetry change in the relative position of the TCNQ− radical molecules sandwiching the TCNQ0 neutral molecule. In addition, the π* electrons, which are localized on the TCNQ− molecules in the low-pressure phase, are delocalized significantly in the high-pressure phase. However, in the high-pressure phase the π* electrons still maintain the localizing character. The charge-transfer degree of the neutral-like and radical-like molecules of the high-pressure phase is estimated to be ρ = 0.46-0.50 and 0.75-0.77, respectively.","subitem_description_type":"Other"}]},"item_16_description_77":{"attribute_name":"URL","attribute_value_mlt":[{"subitem_description":"http://jpsj.ipap.jp/link?JPSJ/72/1784/","subitem_description_type":"Other"}]},"item_16_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Physical Society of Japan"}]},"item_16_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1143/JPSJ.72.1784","subitem_relation_type_select":"DOI"}}]},"item_16_relation_16":{"attribute_name":"情報源(ISSN)","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"00319015"}]}]},"item_16_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2003 The Physical Society of Japan."}]},"item_16_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00704814","subitem_source_identifier_type":"NCID"}]},"item_16_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"431","subitem_subject_scheme":"NDC"}]},"item_16_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"168013 bytes"}]},"item_16_text_47":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"雑誌掲載論文"}]},"item_16_text_48":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Journal Article"}]},"item_16_text_49":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_16_text_50":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"01"}]},"item_16_text_78":{"attribute_name":"コメント","attribute_value_mlt":[{"subitem_text_value":"黒田規敬: 熊本大学大学院自然科学研究科マテリアル工学講座・工学部マテリアル工学科"}]},"item_16_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Hasanudin"}],"nameIdentifiers":[{"nameIdentifier":"95372","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kuroda, Noritaka"}],"nameIdentifiers":[{"nameIdentifier":"95373","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kagayama, Tomoko"}],"nameIdentifiers":[{"nameIdentifier":"95374","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"杉本, 豊成","creatorNameLang":"ja"},{"creatorName":"スギモト, トヨナリ","creatorNameLang":"ja-Kana"},{"creatorName":"Sugimoto, Toyonari","creatorNameLang":"en"}],"familyNames":[{"familyName":"杉本","familyNameLang":"ja"},{"familyName":"スギモト","familyNameLang":"ja-Kana"},{"familyName":"Sugimoto","familyNameLang":"en"}],"givenNames":[{"givenName":"豊成","givenNameLang":"ja"},{"givenName":"トヨナリ","givenNameLang":"ja-Kana"},{"givenName":"Toyonari","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95371","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"小林, 融弘","creatorNameLang":"ja"},{"creatorName":"コバヤシ, ミチヒロ","creatorNameLang":"ja-Kana"},{"creatorName":"Kobayashi, Michihiro","creatorNameLang":"en"}],"familyNames":[{"familyName":"小林","familyNameLang":"ja"},{"familyName":"コバヤシ","familyNameLang":"ja-Kana"},{"familyName":"Kobayashi","familyNameLang":"en"}],"givenNames":[{"givenName":"融弘","givenNameLang":"ja"},{"givenName":"ミチヒロ","givenNameLang":"ja-Kana"},{"givenName":"Michihiro","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95385","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-02"}],"displaytype":"detail","filename":"論文[14].pdf","filesize":[{"value":"168.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"論文[14].pdf","url":"https://kumadai.repo.nii.ac.jp/record/22005/files/論文[14].pdf"},"version_id":"f6ae96ba-b3af-446b-9ce8-44af0b64510b"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"TCNQ compounds","subitem_subject_scheme":"Other"},{"subitem_subject":"insulator to metal transition","subitem_subject_scheme":"Other"},{"subitem_subject":"high pressure","subitem_subject_scheme":"Other"},{"subitem_subject":"infrared","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Pressure dependence of charge distribution along TCNQ columns in Cs2TCNQ3","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Pressure dependence of charge distribution along TCNQ columns in Cs2TCNQ3"}]},"item_type_id":"16","owner":"1","path":["428"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-01-26"},"publish_date":"2009-01-26","publish_status":"0","recid":"22005","relation_version_is_last":true,"title":["Pressure dependence of charge distribution along TCNQ columns in Cs2TCNQ3"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-09-14T07:50:23.854245+00:00"}