{"created":"2023-06-19T09:10:30.674686+00:00","id":22014,"links":{},"metadata":{"_buckets":{"deposit":"3d883b6e-bd63-4326-af5c-cea5e2ddfee4"},"_deposit":{"created_by":1,"id":"22014","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"22014"},"status":"published"},"_oai":{"id":"oai:kumadai.repo.nii.ac.jp:00022014","sets":["426:428"]},"author_link":["95498","95371","95497","95499","95491","95489","95490"],"item_16_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2002-11-11","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"44","bibliographicPageEnd":"10422","bibliographicPageStart":"10419","bibliographicVolumeNumber":"14","bibliographic_titles":[{"bibliographic_title":"Journal of Physics. Condensed Matter"}]}]},"item_16_creator_3":{"attribute_name":"別言語の著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"黒田, 規敬"}],"nameIdentifiers":[{"nameIdentifier":"95497","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"加賀山, 朋子"}],"nameIdentifiers":[{"nameIdentifier":"95498","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"杉本, 豊成"}],"nameIdentifiers":[{"nameIdentifier":"95499","nameIdentifierScheme":"WEKO"}]}]},"item_16_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_16_description_46":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"論文(Article)","subitem_description_type":"Other"}]},"item_16_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Pressure dependence of several molecular vibration modes in Cs2TCNQ3 has been observed through the infrared absorption measurements. The behavior of the C-CN and C-H stretching modes suggests that phase transition takes place at around 3.6 GPa. The π* electrons, which are localized on TCNQ- molecules in the low-pressure phase, are delocalized significantly in the high-pressure phase. However, the radical-like and neutral-like molecules still coexist in the high-pressure phase indicating that the electrons are not completely delocalized. The electron-molecular-vibration (emv) coupled mode disappears in the high-pressure phase in coincident with the disappearance of the inter-radical charge transfer band S1, proving the strong coupling between them.","subitem_description_type":"Other"}]},"item_16_description_77":{"attribute_name":"URL","attribute_value_mlt":[{"subitem_description":"http://www.iop.org/EJ/abstract/0953-8984/14/44/304","subitem_description_type":"Other"}]},"item_16_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Institute of Physics Publishing"}]},"item_16_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1088/0953-8984/14/44/304","subitem_relation_type_select":"DOI"}}]},"item_16_relation_16":{"attribute_name":"情報源(ISSN)","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"09538984"}]}]},"item_16_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2002 Institute of Physics and IOP Publishing Limited"}]},"item_16_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA10672168","subitem_source_identifier_type":"NCID"}]},"item_16_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"431.5","subitem_subject_scheme":"NDC"}]},"item_16_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"80576 bytes"}]},"item_16_text_47":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"雑誌掲載論文"}]},"item_16_text_48":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Journal Article"}]},"item_16_text_49":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_16_text_50":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"01"}]},"item_16_text_78":{"attribute_name":"コメント","attribute_value_mlt":[{"subitem_text_value":"黒田規敬: 熊本大学大学院自然科学研究科マテリアル工学講座・工学部マテリアル工学科"}]},"item_16_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Hasanudin"}],"nameIdentifiers":[{"nameIdentifier":"95489","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kuroda, Noritaka"}],"nameIdentifiers":[{"nameIdentifier":"95490","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kagayama, Tomoko"}],"nameIdentifiers":[{"nameIdentifier":"95491","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"杉本, 豊成","creatorNameLang":"ja"},{"creatorName":"スギモト, トヨナリ","creatorNameLang":"ja-Kana"},{"creatorName":"Sugimoto, Toyonari","creatorNameLang":"en"}],"familyNames":[{"familyName":"杉本","familyNameLang":"ja"},{"familyName":"スギモト","familyNameLang":"ja-Kana"},{"familyName":"Sugimoto","familyNameLang":"en"}],"givenNames":[{"givenName":"豊成","givenNameLang":"ja"},{"givenName":"トヨナリ","givenNameLang":"ja-Kana"},{"givenName":"Toyonari","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95371","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-02"}],"displaytype":"detail","filename":"論文[12].pdf","filesize":[{"value":"80.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"論文[12].pdf","url":"https://kumadai.repo.nii.ac.jp/record/22014/files/論文[12].pdf"},"version_id":"5e6295a9-9947-4a96-8cdb-14b18e14e4ae"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Infrared study on pressure-induced charge delocalization in Cs2TCNQ3","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Infrared study on pressure-induced charge delocalization in Cs2TCNQ3"}]},"item_type_id":"16","owner":"1","path":["428"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-01-26"},"publish_date":"2009-01-26","publish_status":"0","recid":"22014","relation_version_is_last":true,"title":["Infrared study on pressure-induced charge delocalization in Cs2TCNQ3"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-09-14T07:50:21.772859+00:00"}