{"created":"2023-06-19T09:10:30.804272+00:00","id":22017,"links":{},"metadata":{"_buckets":{"deposit":"2fccc8f6-49c0-4138-a17c-c5bdc625f055"},"_deposit":{"created_by":1,"id":"22017","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"22017"},"status":"published"},"_oai":{"id":"oai:kumadai.repo.nii.ac.jp:00022017","sets":["426:428"]},"author_link":["95546","95553","95547","95552","95371"],"item_16_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2005-12-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"155","bibliographicPageStart":"147","bibliographicVolumeNumber":"442","bibliographic_titles":[{"bibliographic_title":"Molecular Crystals and Liquid Crystals"}]}]},"item_16_creator_3":{"attribute_name":"別言語の著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"黒田, 規敬"}],"nameIdentifiers":[{"nameIdentifier":"95552","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"杉本, 豊成"}],"nameIdentifiers":[{"nameIdentifier":"95553","nameIdentifierScheme":"WEKO"}]}]},"item_16_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_16_description_46":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"論文(Article)","subitem_description_type":"Other"}]},"item_16_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"High-pressure infrared absorption has been measured in the single crystals of (TEDA)2TCNQ3 at room temperature. An energy gap of a direct type with the size of approximately 0.23 eV is observed at ambient pressure. In the molecular vibration region, the absorption peaks due to the C=C stretching are observed at 1518 and 1504 cm-1, suggesting that the excess electrons are less localized in this substance compared to other 2:3 TCNQ complexes. The behavior of these peaks suggests that a phase transition takes place at 1.0 GPa. In the high-pressure phase the excess electrons tend to be more localized instead of being delocalized as indicated by the increasing of the energy spacing of those modes. The charge transfer degrees of the TCNQ molecules are estimated to be 0.60 and 0.80 (low pressure) and 0.56 and 0.88 (high-pressure phase).","subitem_description_type":"Other"}]},"item_16_description_77":{"attribute_name":"URL","attribute_value_mlt":[{"subitem_description":"http://www.informaworld.com/openurl?genre=article&issn=1563-5287&volume=442&issue=1&spage=147","subitem_description_type":"Other"}]},"item_16_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Taylor & Francis"}]},"item_16_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1080/154214090964681","subitem_relation_type_select":"DOI"}}]},"item_16_relation_16":{"attribute_name":"情報源(ISSN)","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"15421406"}]}]},"item_16_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2005 Taylor & Francis"}]},"item_16_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11836169","subitem_source_identifier_type":"NCID"}]},"item_16_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"431","subitem_subject_scheme":"NDC"}]},"item_16_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"87849 bytes"}]},"item_16_text_47":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"雑誌掲載論文"}]},"item_16_text_48":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Journal Article"}]},"item_16_text_49":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_16_text_50":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"01"}]},"item_16_text_78":{"attribute_name":"コメント","attribute_value_mlt":[{"subitem_text_value":"黒田規敬: 熊本大学大学院自然科学研究科マテリアル工学講座・工学部マテリアル工学科"}]},"item_16_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Hasanudin"}],"nameIdentifiers":[{"nameIdentifier":"95546","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kuroda, Noritaka"}],"nameIdentifiers":[{"nameIdentifier":"95547","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"杉本, 豊成","creatorNameLang":"ja"},{"creatorName":"スギモト, トヨナリ","creatorNameLang":"ja-Kana"},{"creatorName":"Sugimoto, Toyonari","creatorNameLang":"en"}],"familyNames":[{"familyName":"杉本","familyNameLang":"ja"},{"familyName":"スギモト","familyNameLang":"ja-Kana"},{"familyName":"Sugimoto","familyNameLang":"en"}],"givenNames":[{"givenName":"豊成","givenNameLang":"ja"},{"givenName":"トヨナリ","givenNameLang":"ja-Kana"},{"givenName":"Toyonari","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95371","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-02"}],"displaytype":"detail","filename":"論文[16].pdf","filesize":[{"value":"87.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"論文[16].pdf","url":"https://kumadai.repo.nii.ac.jp/record/22017/files/論文[16].pdf"},"version_id":"a26c3d57-1bb8-4f1b-9d6d-a4a58d74e669"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Electron localization","subitem_subject_scheme":"Other"},{"subitem_subject":"High pressure","subitem_subject_scheme":"Other"},{"subitem_subject":"Infrared spectroscopy","subitem_subject_scheme":"Other"},{"subitem_subject":"TCNQ complexes","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Pressure dependence of electron distribution along the TCNQ columns in (TEDA)2TCNQ3","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Pressure dependence of electron distribution along the TCNQ columns in (TEDA)2TCNQ3"}]},"item_type_id":"16","owner":"1","path":["428"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-01-27"},"publish_date":"2009-01-27","publish_status":"0","recid":"22017","relation_version_is_last":true,"title":["Pressure dependence of electron distribution along the TCNQ columns in (TEDA)2TCNQ3"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-09-14T07:50:21.494316+00:00"}