{"created":"2023-06-19T09:10:40.128373+00:00","id":22198,"links":{},"metadata":{"_buckets":{"deposit":"e2307eef-2bbc-48cc-a58a-c1470ef10ef6"},"_deposit":{"created_by":1,"id":"22198","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"22198"},"status":"published"},"_oai":{"id":"oai:kumadai.repo.nii.ac.jp:00022198","sets":["448:449"]},"author_link":["147103","96443","96432","96444","96434","147102","96435","96433"],"item_16_alternative_title_22":{"attribute_name":"その他の言語のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Flow injection analysis of trace amounts of iodide ion using a catalytic method"}]},"item_16_alternative_title_23":{"attribute_name":"タイトル（ヨミ）","attribute_value_mlt":[{"subitem_alternative_title":"フローインジェクションホウ ニ ヨル ゴクビリョウ ヨウカブツ イオン ノ セッショク ブンセキ テイリョウ"}]},"item_16_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1983-01-05","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"28","bibliographicPageStart":"23","bibliographicVolumeNumber":"32","bibliographic_titles":[{"bibliographic_title":"分析化学"}]}]},"item_16_creator_3":{"attribute_name":"別言語の著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"Deguchi, Toshio","creatorNameLang":"en"},{"creatorName":"出口, 俊雄","creatorNameLang":"ja"},{"creatorName":"デグチ, トシオ","creatorNameLang":"ja-Kana"}],"familyNames":[{"familyName":"Deguchi","familyNameLang":"en"},{"familyName":"出口","familyNameLang":"ja"},{"familyName":"デグチ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":"Toshio","givenNameLang":"en"},{"givenName":"俊雄","givenNameLang":"ja"},{"givenName":"トシオ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"147103","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"田中, 明","creatorNameLang":"ja"},{"creatorName":"タナカ, アキラ","creatorNameLang":"ja-Kana"},{"creatorName":"Tanaka, Akira","creatorNameLang":"en"}],"familyNames":[{"familyName":"田中","familyNameLang":"ja"},{"familyName":"タナカ","familyNameLang":"ja-Kana"},{"familyName":"Tanaka","familyNameLang":"en"}],"givenNames":[{"givenName":"明","givenNameLang":"ja"},{"givenName":"アキラ","givenNameLang":"ja-Kana"},{"givenName":"Akira","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"96433","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"實政, 勲","creatorNameLang":"ja"},{"creatorName":"Sanemasa, Isao","creatorNameLang":"en"},{"creatorName":"サネマサ, イサオ","creatorNameLang":"ja-Kana"}],"familyNames":[{"familyName":"實政","familyNameLang":"ja"},{"familyName":"Sanemasa","familyNameLang":"en"},{"familyName":"サネマサ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":"勲","givenNameLang":"ja"},{"givenName":"Isao","givenNameLang":"en"},{"givenName":"イサオ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"147102","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nagai, Hideo"}],"nameIdentifiers":[{"nameIdentifier":"96443","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"實政, 勲"}],"nameIdentifiers":[{"nameIdentifier":"96444","nameIdentifierScheme":"WEKO"}]}]},"item_16_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_16_description_46":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"雑誌掲載論文","subitem_description_type":"Other"}]},"item_16_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"A sensitive, rapid, and simple method has been developed for the determination of trace amounts of iodide ion by means of flow injection analysis based on the catalytic reduction of sulfatocerium (IV) ion by\narsenic trioxide in sulfuric acid. A sample solution was injected into a redistilled water stream which flowed together with the pre-mixed cerium (IV) and arsenic trioxide in sulfuric acid solution. The sample in the reagent stream was first heated to 60 ℃ to promote the reaction and then cooled to 20 ℃ before being passed into a flow cell. The detection is based on a discoloration of the trisulfatocerium (IV) complex at 312 nm by spectrophotometer equipped with the flow cell (volume 8 μl, light path 10 mm). The optimal conditions were as follows; cerium (IV) : 1.30x 10 -3M in 1.00 M sulfuric acid (flow rate, 1.06 ml/min), arsenic trioxide: 2.40X 10-2 M in 1.00 M sulfuric acid (flow rate, 1.07 ml/min), flow rate of redistilled water: 4.22 ml/min, reaction time: 0.67 min, reagent mixing tube: 180 cm(0.2 cm i.d.), heating tube: 136cm(0.2 cm i.d.), cooling tube: 67 cm(0.2 cm i.d.), sample volume: 2.69 ml. A linear relationship was obtained\nbetween the peak height (absorbance change based on a discoloration) and concentration of iodide ion in the range of 0～50 ppb. The detection limit (S/N: 2) was 1 ppb iodide ion. The sampling rate was 30 samples/h. The reactivity of the sulfatocerium (IV) complexes varied with the number of ligands. The trisulfato complex showed a remarkable catalytic reactivity, whereas the monosulfato complex showed no obvious reactivity. It was found that thiocyanate ion showed high positive interference. Iodide ion in rainwater was determined by the standard addition method without preconcentration. The iodide ion content in rainwater was (1～2) ppb (R.S.D.10 %).","subitem_description_type":"Other"}]},"item_16_description_77":{"attribute_name":"URL","attribute_value_mlt":[{"subitem_description":"http://www.jsac.or.jp/bunka/bunsekikagaku.html","subitem_description_type":"Other"}]},"item_16_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本分析化学会"}]},"item_16_relation_16":{"attribute_name":"情報源(ISSN)","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"05251931"}]}]},"item_16_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"社団法人日本分析化学会"}]},"item_16_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00222633","subitem_source_identifier_type":"NCID"}]},"item_16_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"433","subitem_subject_scheme":"NDC"}]},"item_16_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"409674 bytes"}]},"item_16_text_47":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"雑誌掲載論文"}]},"item_16_text_48":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Journal Article"}]},"item_16_text_49":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_16_text_50":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"01"}]},"item_16_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"出口, 俊雄"}],"nameIdentifiers":[{"nameIdentifier":"96432","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"田中, 明","creatorNameLang":"ja"},{"creatorName":"タナカ, アキラ","creatorNameLang":"ja-Kana"},{"creatorName":"Tanaka, Akira","creatorNameLang":"en"}],"familyNames":[{"familyName":"田中","familyNameLang":"ja"},{"familyName":"タナカ","familyNameLang":"ja-Kana"},{"familyName":"Tanaka","familyNameLang":"en"}],"givenNames":[{"givenName":"明","givenNameLang":"ja"},{"givenName":"アキラ","givenNameLang":"ja-Kana"},{"givenName":"Akira","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"96433","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"実政, 勲"}],"nameIdentifiers":[{"nameIdentifier":"96434","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"永井, 英夫"}],"nameIdentifiers":[{"nameIdentifier":"96435","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-02"}],"displaytype":"detail","filename":"0525-1931v32_023.pdf","filesize":[{"value":"409.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"0525-1931v32_023.pdf","url":"https://kumadai.repo.nii.ac.jp/record/22198/files/0525-1931v32_023.pdf"},"version_id":"3b650de8-ef6f-4899-aff8-d63a4edae8e1"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"How injection analysis of iodide","subitem_subject_scheme":"Other"},{"subitem_subject":"catalytic reaction","subitem_subject_scheme":"Other"},{"subitem_subject":"determination of iodide in rainwater","subitem_subject_scheme":"Other"},{"subitem_subject":"spectrophotometry","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"フローインジェクション法による極微量ヨウ化物イオンの接触分析定量","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"フローインジェクション法による極微量ヨウ化物イオンの接触分析定量"}]},"item_type_id":"16","owner":"1","path":["449"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-02-27"},"publish_date":"2009-02-27","publish_status":"0","recid":"22198","relation_version_is_last":true,"title":["フローインジェクション法による極微量ヨウ化物イオンの接触分析定量"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-09-07T07:58:31.966277+00:00"}