{"created":"2023-06-19T09:10:40.912317+00:00","id":22212,"links":{},"metadata":{"_buckets":{"deposit":"cda708c8-3ccf-4d72-98f1-afc16e4a455a"},"_deposit":{"created_by":1,"id":"22212","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"22212"},"status":"published"},"_oai":{"id":"oai:kumadai.repo.nii.ac.jp:00022212","sets":["448:449"]},"author_link":["147103","96572","96564","96560","147102","96559","96575","96577","96573","96561","96550","96563"],"item_16_alternative_title_22":{"attribute_name":"その他の言語のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Concentration of metal ions in water as electrically neutral complexes on a polytetrafluoroethylene film"}]},"item_16_alternative_title_23":{"attribute_name":"タイトル（ヨミ）","attribute_value_mlt":[{"subitem_alternative_title":"ポリテトラフルオロエチレン フィルム ニ ヨル スイヨウエキチュウ ノ ムデンカ キンゾク サクタイ ノ 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aq. solution of 400 to 500 ml. Chloroform vapor was introduced into the solution and circulated in a closed system for 30 min. Then, the film was picked up and the solute held on it was eluted with CHCl3. As solutes, Hg(II), Pb(II), Ag(I) and Cd(II)-dithizonates and Co(II), Ni(II), Gd(II) and Zn(II)-PAN complexes were used\n(dithizone: diphenylthiocarbazone; PAN: l-(2-pyridylazo)-2-naphthol). For Cd(II)-PAN benzene vapor was circulated, and for Zn(II)-PAN, CHCl3 vapor was circulated for 1 h. Recoveries of metal dithizonates and PAN complexes were more than 80%. In an acidic solution, free dithizone is collected almost completely by the PTFE film, but can be re- B moved from the film while keeping metal dithizonates on the film by circulating CHCl3 vapor in an alkaline solution. When air or carbon tetrachloride vapor was circulated, metal complexes were not collected by the PTFE film. The PTFE film surface is assumed to be covered with a thin layer of liquid CHCl3 upon circulating CHCl3 vapor in aq. solution. The present method is applicable to solutes with a large　chloroform/water partition constant.","subitem_description_type":"Other"}]},"item_16_description_77":{"attribute_name":"URL","attribute_value_mlt":[{"subitem_description":"http://www.jsac.or.jp/bunka/bunsekikagaku.html","subitem_description_type":"Other"}]},"item_16_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本分析化学会"}]},"item_16_relation_16":{"attribute_name":"情報源(ISSN)","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"05251931"}]}]},"item_16_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"社団法人日本分析化学会"}]},"item_16_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00222633","subitem_source_identifier_type":"NCID"}]},"item_16_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"433","subitem_subject_scheme":"NDC"}]},"item_16_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"416145 bytes"}]},"item_16_text_47":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"雑誌掲載論文"}]},"item_16_text_48":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Journal Article"}]},"item_16_text_49":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_16_text_50":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"01"}]},"item_16_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"実政, 勲"}],"nameIdentifiers":[{"nameIdentifier":"96559","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"牛嶋, 隆士"}],"nameIdentifiers":[{"nameIdentifier":"96560","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"林田, 禎子"}],"nameIdentifiers":[{"nameIdentifier":"96561","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"Tochihara, Takuo","creatorNameLang":"en"},{"creatorName":"栃原, 拓夫","creatorNameLang":"ja"},{"creatorName":"トチハラ, タクオ","creatorNameLang":"ja-Kana"}],"familyNames":[{"familyName":"Tochihara","familyNameLang":"en"},{"familyName":"栃原","familyNameLang":"ja"},{"familyName":"トチハラ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":"Takuo","givenNameLang":"en"},{"givenName":"拓夫","givenNameLang":"ja"},{"givenName":"タクオ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"96550","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"石橋, 和也"}],"nameIdentifiers":[{"nameIdentifier":"96563","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"出口, 俊雄"}],"nameIdentifiers":[{"nameIdentifier":"96564","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-02"}],"displaytype":"detail","filename":"0525-1931v42_479.pdf","filesize":[{"value":"416.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"0525-1931v42_479.pdf","url":"https://kumadai.repo.nii.ac.jp/record/22212/files/0525-1931v42_479.pdf"},"version_id":"0513db7d-b43e-48ba-bcf3-98e87e709db5"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"concentration of metal complexes on polytetrafiloroethylene film","subitem_subject_scheme":"Other"},{"subitem_subject":"metal-diphenylthiocarbazone complexes","subitem_subject_scheme":"Other"},{"subitem_subject":"metal-1-(2-pyridylazo)-2-naphthol complexes","subitem_subject_scheme":"Other"},{"subitem_subject":"chlorofbrm/water partltlon","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ポリテトラフルオロエチレンフィルムによる水溶液中の無電荷金属錯体の濃縮","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ポリテトラフルオロエチレンフィルムによる水溶液中の無電荷金属錯体の濃縮"}]},"item_type_id":"16","owner":"1","path":["449"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-02-27"},"publish_date":"2009-02-27","publish_status":"0","recid":"22212","relation_version_is_last":true,"title":["ポリテトラフルオロエチレンフィルムによる水溶液中の無電荷金属錯体の濃縮"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-08-21T02:44:48.882839+00:00"}