{"created":"2023-06-19T09:10:41.562628+00:00","id":22225,"links":{},"metadata":{"_buckets":{"deposit":"c3ca3401-a5ee-4e2d-8dbf-6b57080938b8"},"_deposit":{"created_by":1,"id":"22225","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"22225"},"status":"published"},"_oai":{"id":"oai:kumadai.repo.nii.ac.jp:00022225","sets":["448:449"]},"author_link":["147103","96686","96700","96688","96690","96698","96699","147102","96689","96433","96687","96685"],"item_16_alternative_title_22":{"attribute_name":"その他の言語のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Flow Injection Analysis of Cyanide Using Immobilized Enzyme"}]},"item_16_alternative_title_23":{"attribute_name":"タイトル（ヨミ）","attribute_value_mlt":[{"subitem_alternative_title":"コテイカ コウソ オ リヨウ シタ シアンカブツ ノ フロー インジェクション ブンセキホウ"}]},"item_16_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1996-12","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"147","bibliographicPageStart":"138","bibliographicVolumeNumber":"13","bibliographic_titles":[{"bibliographic_title":"Journal of Flow Injection Analysis"}]}]},"item_16_creator_3":{"attribute_name":"別言語の著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"Deguchi, Toshio","creatorNameLang":"en"},{"creatorName":"出口, 俊雄","creatorNameLang":"ja"},{"creatorName":"デグチ, トシオ","creatorNameLang":"ja-Kana"}],"familyNames":[{"familyName":"Deguchi","familyNameLang":"en"},{"familyName":"出口","familyNameLang":"ja"},{"familyName":"デグチ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":"Toshio","givenNameLang":"en"},{"givenName":"俊雄","givenNameLang":"ja"},{"givenName":"トシオ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"147103","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Fukaura, Kouichi"}],"nameIdentifiers":[{"nameIdentifier":"96698","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Norimatsu, Shigeko"}],"nameIdentifiers":[{"nameIdentifier":"96699","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Minami, Sayuri"}],"nameIdentifiers":[{"nameIdentifier":"96700","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"田中, 明","creatorNameLang":"ja"},{"creatorName":"タナカ, アキラ","creatorNameLang":"ja-Kana"},{"creatorName":"Tanaka, Akira","creatorNameLang":"en"}],"familyNames":[{"familyName":"田中","familyNameLang":"ja"},{"familyName":"タナカ","familyNameLang":"ja-Kana"},{"familyName":"Tanaka","familyNameLang":"en"}],"givenNames":[{"givenName":"明","givenNameLang":"ja"},{"givenName":"アキラ","givenNameLang":"ja-Kana"},{"givenName":"Akira","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"96433","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"實政, 勲","creatorNameLang":"ja"},{"creatorName":"Sanemasa, Isao","creatorNameLang":"en"},{"creatorName":"サネマサ, イサオ","creatorNameLang":"ja-Kana"}],"familyNames":[{"familyName":"實政","familyNameLang":"ja"},{"familyName":"Sanemasa","familyNameLang":"en"},{"familyName":"サネマサ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":"勲","givenNameLang":"ja"},{"givenName":"Isao","givenNameLang":"en"},{"givenName":"イサオ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"147102","nameIdentifierScheme":"WEKO"}]}]},"item_16_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_16_description_46":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"論文(Article)","subitem_description_type":"Other"}]},"item_16_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"A flow-injection system with an immobilized enzyme reactor is proposed for the determination of cyanide. The system includes the rhodanese immobilized on aminopropy1-control led pore glass beads, which acts as an enzyme reactor. In this system, cyanide is converted to thiocyanate in the presence of thiosulfate in the immobilized enzyme reactor, then the thiocyanate forms iron(l) thiocyanate complex, which is spectrophotometrically detected at 460 nm. The optimum conditions in the flow-injection system are proposed. Under the optimized condition, the detection limit(S/N = 3) of cyanide was 15 pM and the linear relationship was obtained in the range of 0-1 mM cyanide. The sample frequency was 20 /h. The precision of the method was 2. 3 % relative standard deviation at 0.5 mM cyanide. The immobilized rhodanese was stable for at least 10 h of continuous operation. Also it retained 91 % of the initial activity after 1 week, 83 % after 1 month. Many kinds of anions which commonly interfere with the determination of cyanide except ascorbate did not interfere in the present method. The flow-injection\nsystem developed here is applicable to the determination of cyanide in environ mental and clinical samples.","subitem_description_type":"Other"}]},"item_16_description_77":{"attribute_name":"URL","attribute_value_mlt":[{"subitem_description":"http://aitech.ac.jp/~jafia/japanese/index.html","subitem_description_type":"Other"}]},"item_16_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"（社）日本分析化学会フローインジェクション分析研究懇談会(JAFIA)"}]},"item_16_relation_16":{"attribute_name":"情報源(ISSN)","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"0911775X"}]}]},"item_16_relation_53":{"attribute_name":"著作の一部","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://aitech.ac.jp/~jafia/"}]}]},"item_16_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA10962565","subitem_source_identifier_type":"NCID"}]},"item_16_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"433","subitem_subject_scheme":"NDC"}]},"item_16_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"837616 bytes"}]},"item_16_text_47":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"雑誌掲載論文"}]},"item_16_text_48":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Journal Article"}]},"item_16_text_49":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_16_text_50":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"01"}]},"item_16_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"出口, 俊雄"}],"nameIdentifiers":[{"nameIdentifier":"96685","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"深浦, 康一"}],"nameIdentifiers":[{"nameIdentifier":"96686","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"則松, 成子"}],"nameIdentifiers":[{"nameIdentifier":"96687","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"南, 小百合"}],"nameIdentifiers":[{"nameIdentifier":"96688","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"田中, 明"}],"nameIdentifiers":[{"nameIdentifier":"96689","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"實政, 勲"}],"nameIdentifiers":[{"nameIdentifier":"96690","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-02"}],"displaytype":"detail","filename":"0911-775X_13-138.pdf","filesize":[{"value":"837.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"0911-775X_13-138.pdf","url":"https://kumadai.repo.nii.ac.jp/record/22225/files/0911-775X_13-138.pdf"},"version_id":"473eba82-5a02-40c2-b550-36d280966103"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"固定化酵素を利用したシアン化物のフローインジェクション分析法","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"固定化酵素を利用したシアン化物のフローインジェクション分析法"}]},"item_type_id":"16","owner":"1","path":["449"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-02-27"},"publish_date":"2009-02-27","publish_status":"0","recid":"22225","relation_version_is_last":true,"title":["固定化酵素を利用したシアン化物のフローインジェクション分析法"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-09-07T07:58:31.687766+00:00"}