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Manganese (III) Acetate-Catalyzed Oxidation of 4-Piperidone-3-carboxylates in the Presence of 1,1-Disubstituted Alkenes
http://hdl.handle.net/2298/12270
http://hdl.handle.net/2298/12270f5b0e8af-de67-41fc-9610-f09fdc2ad5d5
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
KT0014_001-006.pdf (433.5 kB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2009-09-07 | |||||
| タイトル | ||||||
| タイトル | Manganese (III) Acetate-Catalyzed Oxidation of 4-Piperidone-3-carboxylates in the Presence of 1,1-Disubstituted Alkenes | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ | departmental bulletin paper | |||||
| 著者 |
Kumabe, Ryoko
× Kumabe, Ryoko× 西野, 宏 |
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| 別言語の著者 |
隈部, 了浩
× 隈部, 了浩× Nishino, Hiroshi |
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| 内容記述 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | The manganese(III) acetate-catalyzed cycloperoxidation of 4-piperidone-3-carboxylates with 1,1-disubstituted alkenes is described. The 4-piperidone-3-carboxylates reacted with 1,1-disubstituted alkenes in the presence of a catalytic amount of manganese(III) acetate in air at 23 ℃ to give 1-hydroxy-8-aza-2,3-dioxabicyclo[4.4.0]-decane-6-carboxylates in good to moderate yields. The crystal structure of the azabicyclic peroxides was determined by an X-ray single crystal analysis. The oxidation of the 4-piperidone-3-carboxylates with 1,1-diphenylethene using a stoichiometric amount of manganese(III) acetate gave ethenyl- and ethyl-substituted 4-piperidones and 6-hydroxy-3-aza-7-oxabicyclo[4.3.0]nonane-1-carboxylate which was the same as the product obtained from the hydrogenolysis of the 1-hydroxy-8-aza-2,3-dioxabicyclo[4.4.0]decane-6-carboxylate. | |||||
| 書誌情報 |
熊本大学極低温装置室ユーザー研究報告書 : 熊大極低温 巻 14, p. 1-6, 発行年 2003-10 |
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| NCID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA12112448 | |||||
| フォーマット | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | application/pdf | |||||
| 形態 | ||||||
| 433457 bytes | ||||||
| 著者版フラグ | ||||||
| 出版タイプ | AM | |||||
| 日本十進分類法 | ||||||
| 主題Scheme | NDC | |||||
| 主題 | 436 | |||||
| 出版者 | ||||||
| 出版者 | 熊本大学 | |||||
| 資源タイプ | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | 論文(Article) | |||||
| 資源タイプ・ローカル | ||||||
| 紀要論文 | ||||||
| 資源タイプ・NII | ||||||
| Departmental Bulletin Paper | ||||||
| 資源タイプ・DCMI | ||||||
| text | ||||||
| 資源タイプ・ローカル表示コード | ||||||
| 02 | ||||||
