{"created":"2023-06-19T09:11:02.504054+00:00","id":22656,"links":{},"metadata":{"_buckets":{"deposit":"be84aadc-842a-43d4-9ee7-6212c8633717"},"_deposit":{"created_by":1,"id":"22656","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"22656"},"status":"published"},"_oai":{"id":"oai:kumadai.repo.nii.ac.jp:00022656","sets":["407:446:1313","585:596:1316"]},"author_link":["160133","160135","160136","160134"],"item_15_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2008-03","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"9","bibliographicPageStart":"5","bibliographicVolumeNumber":"18","bibliographic_titles":[{"bibliographic_title":"熊本大学極低温装置室ユーザー研究報告書 : 熊大極低温"}]}]},"item_15_creator_3":{"attribute_name":"別言語の著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"[伊藤, 洋輔]"}],"nameIdentifiers":[{"nameIdentifier":"160135","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nishino, Hiroshi"}],"nameIdentifiers":[{"nameIdentifier":"160136","nameIdentifierScheme":"WEKO"}]}]},"item_15_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_15_description_46":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"論文(Article)","subitem_description_type":"Other"}]},"item_15_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Manganese(III)-based oxidative free-radical macrocyclization was examined. α,α,ω,ω-Tetraaryl-α,ω-alkadienes 1x (x = 6, 8, 12, 16, 18, 28) and oligomethylene bis(3-oxobutanoate)s 2y (y = 6, 10, 12, 16, 20, 26) were allowed to react with manganese(III) acetate in acetic acid at 100 ℃ under an argon atmosphere to give the 20- to 62-membered huge macrocyclic compounds 3xy in good to moderate yields. A similar reaction of alkadienes 45, 72 with bis(3-oxobutanoate)s 57, 81, 82 containing p-phenylene in the alkyl chain also afforded the cyclophane-type macrocyclic compounds 6, 91, 92, 101, 102 in acceptable yields. The mechanism for the formation of the macrodiolides was explained by the production of intramolecular electron donor-acceptor-type complex E between the donor terminal olefin part and the acceptor manganese(III)-enolate moiety.","subitem_description_type":"Other"}]},"item_15_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"熊本大学"}]},"item_15_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12112448","subitem_source_identifier_type":"NCID"}]},"item_15_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"436","subitem_subject_scheme":"NDC"}]},"item_15_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"358372 bytes"}]},"item_15_text_47":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"紀要論文"}]},"item_15_text_48":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Departmental Bulletin Paper"}]},"item_15_text_49":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_15_text_50":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"02"}]},"item_15_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ito, Yosuke"}],"nameIdentifiers":[{"nameIdentifier":"160133","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"西野, 宏"},{"creatorName":"ニシノ, ヒロシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"160134","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-02"}],"displaytype":"detail","filename":"KT0018_005-009.pdf","filesize":[{"value":"358.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KT0018_005-009.pdf","url":"https://kumadai.repo.nii.ac.jp/record/22656/files/KT0018_005-009.pdf"},"version_id":"a4eb3eb9-a51a-4aa1-9b13-a701c4786454"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis of Macrocyclic Compounds Using Oxidative Radical Cyclization","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis of Macrocyclic Compounds Using Oxidative Radical Cyclization"}]},"item_type_id":"15","owner":"1","path":["1313","1316"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-09-08"},"publish_date":"2009-09-08","publish_status":"0","recid":"22656","relation_version_is_last":true,"title":["Synthesis of Macrocyclic Compounds Using Oxidative Radical Cyclization"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-06-19T15:20:52.892555+00:00"}