@article{oai:kumadai.repo.nii.ac.jp:00024205, author = {澤田, 剛 and Sawada, Tsuyoshi and Kuroki, Mizue and 黒木, 瑞恵 and Ogawa, Tomoya and 小川, 智也 and Shimojo, Kentaro and 下城, 健太朗 and Chifuku, Kazufumi and 地福, 寿史 and Ihara, Hirotaka and 伊原, 博隆 and 澤田, 剛 and Sawada, Tsuyoshi and Kuroki, Mizue and 黒木, 瑞恵 and Ogawa, Tomoya and 小川, 智也 and Shimojo, Kentaro and 下城, 健太朗 and Chifuku, Kazufumi and 地福, 寿史 and Ihara, Hirotaka and 伊原, 博隆}, issue = {31}, journal = {Tetrahedron Letters}, month = {Aug}, note = {application/pdf, 論文(Article), In this study, 9,10-diacetoxyl-2,7-di-tert-butyl-trans-10b,10c-dimethyl-10b,10c-dihydropyrene annelated with a dihydrothieno[3.4-b]pyrazine unit (1a) was prepared, for the first time, from 5,13-di-tert-butyl-8,16-dimethyl-1,2,9,10- tetrahydroxy[2.2]metacyclophane and 3,4-diaminothiophene in two steps. The photoisomerization property of 1 was investigated by UV and 1H-NMR spectroscopies, and the quantitative isomerization between the more stable dihydropyrene (DHP) form and the less stable metacyclophane-diene (MCPD) form was observed. A thermally induced return reaction from the MCPD to the DHP form was examined at various temperatures, and the reaction rate was 0.0049 min-1 at 45°C, which is slower than that of the parent MCPD.}, pages = {4033--4036}, title = {Dihydropyrene annelated with dihydrothieno[3.4-b]pyrazine: synthesis and photoswitching property}, volume = {51}, year = {2010}, yomi = {サワダ, ツヨシ and クロキ, ミズエ and オガワ, トモヤ and シモジョウ, ケンタロウ and チフク, カズフミ and イハラ, ヒロタカ and サワダ, ツヨシ and クロキ, ミズエ and オガワ, トモヤ and シモジョウ, ケンタロウ and チフク, カズフミ and イハラ, ヒロタカ} }