{"created":"2023-06-19T09:12:33.869061+00:00","id":24418,"links":{},"metadata":{"_buckets":{"deposit":"6c3970fa-3ddf-4260-a88c-de089aafe600"},"_deposit":{"created_by":1,"id":"24418","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"24418"},"status":"published"},"_oai":{"id":"oai:kumadai.repo.nii.ac.jp:00024418","sets":["448:478"]},"author_link":["146758"],"item_18_alternative_title_22":{"attribute_name":"その他の言語のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Synthesis of Propellane-Type Heterocycles Using Tandem Cyclization"}]},"item_18_alternative_title_23":{"attribute_name":"タイトル（ヨミ）","attribute_value_mlt":[{"subitem_alternative_title":"タンデム カンカ ハンノウ オ リヨウ シタ 3マイ バ フクソ カン プロペラ ガタ カゴウブツ ノ ゴウセイ"}]},"item_18_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-05-12","bibliographicIssueDateType":"Issued"},"bibliographic_titles":[{}]}]},"item_18_creator_3":{"attribute_name":"別言語の著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"Nishino, Hiroshi","creatorNameLang":"en"},{"creatorName":"西野, 宏","creatorNameLang":"ja"},{"creatorName":"ニシノ, ヒロシ","creatorNameLang":"ja-Kana"}],"familyNames":[{"familyName":"Nishino","familyNameLang":"en"},{"familyName":"西野","familyNameLang":"ja"},{"familyName":"ニシノ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":"Hiroshi","givenNameLang":"en"},{"givenName":"宏","givenNameLang":"ja"},{"givenName":"ヒロシ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"146758","nameIdentifierScheme":"WEKO"}]}]},"item_18_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf"}]},"item_18_description_46":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"研究報告書","subitem_description_type":"Other"}]},"item_18_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"タンデム環化反応とは一度環化反応が開始された後、続けて次から次へと分子内環化が起こる反応のことであり、有機環状化合物を合成する効率的な手法として重要である。そこで本研究では酢酸マンガン(III)による酸化的ラジカルタンデム環化反応を用いた新規プロペラ型複素環化合物やシクロファン型大環状化合物合成の開発を行った。プロペラ型複素環化合物や大環状化合物は生理活性や薬理活性が期待され、構造的にも興味がもたれる。","subitem_description_type":"Other"},{"subitem_description":"Tandem cyclization is a successive intramolecular cyclization when the cyclization is once started, and important for the synthesis of organic cyclization compounds as an efficient synthetic technique. In the research project, the synthesis of novel propellane-type heterocyclic compounds and cyclophane-type macrolides using manganese(III) acetate-based oxidative radical tandem cyclization was studied. The biological activities and physicochemical interests of these compounds are expected.","subitem_description_type":"Other"}]},"item_18_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"熊本大学"}]},"item_18_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"438.9","subitem_subject_scheme":"NDC"}]},"item_18_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"84979 bytes"}]},"item_18_text_47":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"研究報告書"}]},"item_18_text_48":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Research Paper"}]},"item_18_text_49":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_18_text_50":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"06"}]},"item_18_text_78":{"attribute_name":"コメント","attribute_value_mlt":[{"subitem_text_value":"平成19～21年度科学研究費補助金(基盤研究(C))研究成果報告書　課題番号：19550046"}]},"item_18_text_80":{"attribute_name":"科研費番号","attribute_value_mlt":[{"subitem_text_value":"19550046"}]},"item_18_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"Nishino, Hiroshi","creatorNameLang":"en"},{"creatorName":"西野, 宏","creatorNameLang":"ja"},{"creatorName":"ニシノ, ヒロシ","creatorNameLang":"ja-Kana"}],"familyNames":[{"familyName":"Nishino","familyNameLang":"en"},{"familyName":"西野","familyNameLang":"ja"},{"familyName":"ニシノ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":"Hiroshi","givenNameLang":"en"},{"givenName":"宏","givenNameLang":"ja"},{"givenName":"ヒロシ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"146758","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-02"}],"displaytype":"detail","filename":"KaC19550046.pdf","filesize":[{"value":"85.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KaC19550046.pdf","url":"https://kumadai.repo.nii.ac.jp/record/24418/files/KaC19550046.pdf"},"version_id":"6675028b-8328-49e3-bc7c-cb3dbf3b676d"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"タンデム環化反応","subitem_subject_scheme":"Other"},{"subitem_subject":"複素環プロペラン類","subitem_subject_scheme":"Other"},{"subitem_subject":"酸化反応","subitem_subject_scheme":"Other"},{"subitem_subject":"ラジカル反応","subitem_subject_scheme":"Other"},{"subitem_subject":"プロペラ型化合物","subitem_subject_scheme":"Other"},{"subitem_subject":"ビシクロ化合物","subitem_subject_scheme":"Other"},{"subitem_subject":"Lewis酸","subitem_subject_scheme":"Other"},{"subitem_subject":"分子内環化反応","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"タンデム環化反応を利用した三枚羽複素環プロペラ型化合物の合成","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"タンデム環化反応を利用した三枚羽複素環プロペラ型化合物の合成"}]},"item_type_id":"18","owner":"1","path":["478"],"pubdate":{"attribute_name":"公開日","attribute_value":"2011-01-19"},"publish_date":"2011-01-19","publish_status":"0","recid":"24418","relation_version_is_last":true,"title":["タンデム環化反応を利用した三枚羽複素環プロペラ型化合物の合成"],"weko_creator_id":"1","weko_shared_id":1},"updated":"2023-08-21T01:42:04.114247+00:00"}