{"created":"2023-06-19T09:14:06.654680+00:00","id":26225,"links":{},"metadata":{"_buckets":{"deposit":"c19f6fc7-61a0-4c96-b0f1-ce0af2a36a5c"},"_deposit":{"created_by":1,"id":"26225","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"26225"},"status":"published"},"_oai":{"id":"oai:kumadai.repo.nii.ac.jp:00026225","sets":["448:449"]},"author_link":["118333","118329","118330","118332","118334","118331"],"item_16_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-10-27","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"347","bibliographicPageStart":"343","bibliographicVolumeNumber":"72","bibliographic_titles":[{"bibliographic_title":"Advances in Science and Technology"}]}]},"item_16_creator_3":{"attribute_name":"別言語の著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"谷口, 祥"}],"nameIdentifiers":[{"nameIdentifier":"118333","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"安仁屋, 勝"}],"nameIdentifiers":[{"nameIdentifier":"118334","nameIdentifierScheme":"WEKO"}]}]},"item_16_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_16_description_46":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"論文(Article)","subitem_description_type":"Other"}]},"item_16_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"In complex perovskite-type oxides which have been studied as cathode materials, the thermal expansion coefficient increases with the increase in the oxygen ionic conductivity. In the present study, with the aim to explain such a behavior, a research has been carried out from a chemical bond point of view. For oxides A1-xA′xB1-yB′yO3-δ with perovskite structure, the ionicity of the individual bond, A-O and B-O, and the thermal expansion coefficient of mixed compounds were estimated by using semiempirical methods. It has been shown that the thermal expansion coefficient and the oxygen ionic conductivity decrease with the increase in the difference of the ionicity between A-O and B-O bonds. It is also found that the tolerance factor and the specific free volume are linearly correlated with the difference of ionicity.","subitem_description_type":"Other"}]},"item_16_description_77":{"attribute_name":"URL","attribute_value_mlt":[{"subitem_description":"http://www.scientific.net/AST.72.343","subitem_description_type":"Other"}]},"item_16_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Trans Tech Publications"}]},"item_16_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.4028/www.scientific.net/AST.72.343","subitem_relation_type_select":"DOI"}}]},"item_16_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2010 Trans Tech Publications"}]},"item_16_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"420","subitem_subject_scheme":"NDC"}]},"item_16_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"180576 bytes"}]},"item_16_text_47":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"雑誌掲載論文"}]},"item_16_text_48":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Journal Article"}]},"item_16_text_49":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_16_text_50":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"01"}]},"item_16_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Taniguchi, Sachi"}],"nameIdentifiers":[{"nameIdentifier":"118329","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Aniya, Masaru"}],"nameIdentifiers":[{"nameIdentifier":"118330","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-02"}],"displaytype":"detail","filename":"AdvSciTech72_2010_343.pdf","filesize":[{"value":"180.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"AdvSciTech72_2010_343.pdf","url":"https://kumadai.repo.nii.ac.jp/record/26225/files/AdvSciTech72_2010_343.pdf"},"version_id":"4be53521-a084-4bdc-9f74-fde05e7bf883"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"ionicity","subitem_subject_scheme":"Other"},{"subitem_subject":"thermal expansion coefficient","subitem_subject_scheme":"Other"},{"subitem_subject":"oxygen ion conductivity","subitem_subject_scheme":"Other"},{"subitem_subject":"perovskite oxides","subitem_subject_scheme":"Other"},{"subitem_subject":"chemical bonding","subitem_subject_scheme":"Other"},{"subitem_subject":"tolerance factor","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"A Chemical Bonding Approach to Ionic Conduction and Thermal Expansion in Oxide Ion Conductors","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"A Chemical Bonding Approach to Ionic Conduction and Thermal Expansion in Oxide Ion Conductors"}]},"item_type_id":"16","owner":"1","path":["449"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-04-05"},"publish_date":"2012-04-05","publish_status":"0","recid":"26225","relation_version_is_last":true,"title":["A Chemical Bonding Approach to Ionic Conduction and Thermal Expansion in Oxide Ion Conductors"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-06-19T17:52:26.416572+00:00"}