{"created":"2023-06-19T09:14:25.195893+00:00","id":26605,"links":{},"metadata":{"_buckets":{"deposit":"9ebbd2d4-12a5-4664-8121-23204bdf06b9"},"_deposit":{"created_by":1,"id":"26605","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"26605"},"status":"published"},"_oai":{"id":"oai:kumadai.repo.nii.ac.jp:00026605","sets":["448:449"]},"author_link":["146758","120456","120461","120455","120457","143640"],"item_16_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2011-11","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"11","bibliographicPageEnd":"9581","bibliographicPageStart":"9562","bibliographicVolumeNumber":"16","bibliographic_titles":[{"bibliographic_title":"Molecules"}]}]},"item_16_creator_3":{"attribute_name":"別言語の著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"五十嵐, 光"}],"nameIdentifiers":[{"nameIdentifier":"120461","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"Nishino, Hiroshi","creatorNameLang":"en"},{"creatorName":"西野, 宏","creatorNameLang":"ja"},{"creatorName":"ニシノ, ヒロシ","creatorNameLang":"ja-Kana"}],"familyNames":[{"familyName":"Nishino","familyNameLang":"en"},{"familyName":"西野","familyNameLang":"ja"},{"familyName":"ニシノ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":"Hiroshi","givenNameLang":"en"},{"givenName":"宏","givenNameLang":"ja"},{"givenName":"ヒロシ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"146758","nameIdentifierScheme":"WEKO"}]}]},"item_16_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"},{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_16_description_46":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"論文(Article)","subitem_description_type":"Other"}]},"item_16_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"The Mn(III)-initiated aerobic oxidation of heterocyclic 1,3-dicarbonyl\ncompounds, such as 4-alkyl-1,2-diphenylpyrazolidine-3,5-diones, 1,3-dialkylpyrrolidine-\n2,4-diones, 3-alkyl-1,5-dimethylbarbituric acids, and 3-butyl-4-hydroxy-2-quinolinone\ngave excellent to good yields of the corresponding hydroperoxides, which were gradually\ndegraded by exposure to the metal initiator after the reaction to afford the corresponding\nalcohols. The synthesis of 30 heterocyclic 1,3-dicarbonyl compounds, the corresponding\nhydroperoxides and the 10 alcohols, their characterization, and the limitations of the\nprocedure are described. In addition, the mechanism of the hydroperoxidation and the\nredox decomposition of the hydroperoxides are discussed.","subitem_description_type":"Other"}]},"item_16_description_77":{"attribute_name":"URL","attribute_value_mlt":[{"subitem_description":"http://www.mdpi.com/1420-3049/16/11/9562","subitem_description_type":"Other"}]},"item_16_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Molecular Diversity Preservation International"}]},"item_16_relation_10":{"attribute_name":"PubMed番号","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"22089863","subitem_relation_type_select":"PMID"}}]},"item_16_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.3390/molecules16119562","subitem_relation_type_select":"DOI"}}]},"item_16_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"14203049","subitem_source_identifier_type":"ISSN"}]},"item_16_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"430","subitem_subject_scheme":"NDC"}]},"item_16_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"708401 bytes"},{"subitem_text_value":"58277 bytes"}]},"item_16_text_47":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"雑誌掲載論文"}]},"item_16_text_48":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Journal Article"}]},"item_16_text_49":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_16_text_50":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"01"}]},"item_16_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Rahman, Taifur"}],"nameIdentifiers":[{"nameIdentifier":"120455","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Haque, Md. Aminul"}],"nameIdentifiers":[{"nameIdentifier":"120456","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Igarashi, Hikaru"}],"nameIdentifiers":[{"nameIdentifier":"120457","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nishino, Hiroshi"}],"nameIdentifiers":[{"nameIdentifier":"143640","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-02"}],"displaytype":"detail","filename":"Molecules-,2011,16,9562-9581-full version.pdf","filesize":[{"value":"708.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Molecules-,2011,16,9562-9581-full version.pdf","url":"https://kumadai.repo.nii.ac.jp/record/26605/files/Molecules-,2011,16,9562-9581-full version.pdf"},"version_id":"9ea77f56-1f3b-491d-a036-a8759647e988"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"hydroperoxides","subitem_subject_scheme":"Other"},{"subitem_subject":"peroxy radicals","subitem_subject_scheme":"Other"},{"subitem_subject":"aerobic oxidation","subitem_subject_scheme":"Other"},{"subitem_subject":"redox","subitem_subject_scheme":"Other"},{"subitem_subject":"2-hydroxy-1,3- dicarbonyl compounds","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Mn(III)-initiated facile oxygenation of heterocyclic 1,3-dicarbonyl compounds","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Mn(III)-initiated facile oxygenation of heterocyclic 1,3-dicarbonyl compounds"}]},"item_type_id":"16","owner":"1","path":["449"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-07-31"},"publish_date":"2012-07-31","publish_status":"0","recid":"26605","relation_version_is_last":true,"title":["Mn(III)-initiated facile oxygenation of heterocyclic 1,3-dicarbonyl compounds"],"weko_creator_id":"1","weko_shared_id":1},"updated":"2023-08-21T01:42:06.803002+00:00"}