@article{oai:kumadai.repo.nii.ac.jp:00026749,
 author = {清水, 鉄矢 and 小松, 恭佳 and 上畠, 秀允 and Kamihata, Hidenobu and 冬広, 明 and 飯島, 誠一郎 and 速水, 真也 and Hayami, Shinya and Shimizu, Tetsuya and Komatsu, Yasuka and 上畠, 秀允 and Kamihata, Hidenobu and Lee, Young Hoon and Lee, Young Hoon and Fuyuhiro, Akira and Iijima, Seiichiro and 速水, 真也 and Hayami, Shinya},
 issue = {3-4},
 journal = {Journal of Inclusion Phenomena and Macrocyclic Chemistry},
 month = {Dec},
 note = {application/pdf, 論文(Article), Iron(III) spin-crossover compounds, [Fe(qnal)2]CF3SO3・MeOH (1・MeOH) and [Fe(qual)2]CF3SO3・acetone (1・acetone) were prepared and their spin transition properties were characterized by magnetic susceptibility measurement, Mӧssbauer spectroscopy and single crystal analysis. Two iron(III)compounds exhibited abrupt spin transition with thermal hysteresis loop(T1/2↑=115　K and T1/2↓=104 K for 1・MeOH, and T1/2↑=133 K and T1/2↓=130 K for 1・acetone). Single crystal analysis revealed both of the structures in high-spin(HS)and low-spin(LS)states for 1・acetone. The difference of bond length between the HS and LS states for 1・acetone was~0.10 Å, which was corresponding to that of typical iron(III)SCO compounds. Specially, it showed strong intermolecular interactions by π-π stacking formed between the neighbor complexes leading to 2-D sheet. Both 1・MeOH and 1・acetone exhibited LIESST effect when it was illuminated at 1000 nm. We also confirmed that the introduction of strong intermolecular interactions, such as π-π stacking, can play an important role in LIESST effect., http://link.springer.com/article/10.1007%2Fs10847-011-9960-3},
 pages = {363--369},
 title = {Photo-switchable spin-crossover iron(III) compound based on intermolecular interactions},
 volume = {71},
 year = {2011},
 yomi = {カミハタ, ヒデノブ and ハヤミ, シンヤ and カミハタ, ヒデノブ and ハヤミ, シンヤ}
}