{"created":"2023-06-19T09:14:33.355767+00:00","id":26749,"links":{},"metadata":{"_buckets":{"deposit":"7a59cfa5-5f34-47d9-8be5-e653841de55c"},"_deposit":{"created_by":1,"id":"26749","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"26749"},"status":"published"},"_oai":{"id":"oai:kumadai.repo.nii.ac.jp:00026749","sets":["448:449"]},"author_link":["147053","112210","147054","147056","147052","147055","147057"],"item_16_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2011-12","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"3-4","bibliographicPageEnd":"369","bibliographicPageStart":"363","bibliographicVolumeNumber":"71","bibliographic_titles":[{"bibliographic_title":"Journal of Inclusion Phenomena and Macrocyclic Chemistry"}]}]},"item_16_creator_3":{"attribute_name":"別言語の著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"清水, 鉄矢"}],"nameIdentifiers":[{"nameIdentifier":"147052","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"小松, 恭佳"}],"nameIdentifiers":[{"nameIdentifier":"147053","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"上畠, 秀允","creatorNameLang":"ja"},{"creatorName":"カミハタ, ヒデノブ","creatorNameLang":"ja-Kana"},{"creatorName":"Kamihata, Hidenobu","creatorNameLang":"en"}],"familyNames":[{"familyName":"上畠","familyNameLang":"ja"},{"familyName":"カミハタ","familyNameLang":"ja-Kana"},{"familyName":"Kamihata","familyNameLang":"en"}],"givenNames":[{"givenName":"秀允","givenNameLang":"ja"},{"givenName":"ヒデノブ","givenNameLang":"ja-Kana"},{"givenName":"Hidenobu","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"147054","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"冬広, 明"}],"nameIdentifiers":[{"nameIdentifier":"147057","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"飯島, 誠一郎"}],"nameIdentifiers":[{"nameIdentifier":"147056","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"速水, 真也","creatorNameLang":"ja"},{"creatorName":"ハヤミ, シンヤ","creatorNameLang":"ja-Kana"},{"creatorName":"Hayami, Shinya","creatorNameLang":"en"}],"familyNames":[{"familyName":"速水","familyNameLang":"ja"},{"familyName":"ハヤミ","familyNameLang":"ja-Kana"},{"familyName":"Hayami","familyNameLang":"en"}],"givenNames":[{"givenName":"真也","givenNameLang":"ja"},{"givenName":"シンヤ","givenNameLang":"ja-Kana"},{"givenName":"Shinya","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"112210","nameIdentifierScheme":"WEKO"}]}]},"item_16_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_16_description_46":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"論文(Article)","subitem_description_type":"Other"}]},"item_16_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Iron(III) spin-crossover compounds, [Fe(qnal)2]CF3SO3・MeOH (1・MeOH) and [Fe(qual)2]CF3SO3・acetone (1・acetone) were prepared and their spin transition properties were characterized by magnetic susceptibility measurement, Mӧssbauer spectroscopy and single crystal analysis. Two iron(III)compounds exhibited abrupt spin transition with thermal hysteresis loop(T1/2↑=115　K and T1/2↓=104 K for 1・MeOH, and T1/2↑=133 K and T1/2↓=130 K for 1・acetone). Single crystal analysis revealed both of the structures in high-spin(HS)and low-spin(LS)states for 1・acetone. The difference of bond length between the HS and LS states for 1・acetone was~0.10 Å, which was corresponding to that of typical iron(III)SCO compounds. Specially, it showed strong intermolecular interactions by π-π stacking formed between the neighbor complexes leading to 2-D sheet. Both 1・MeOH and 1・acetone exhibited LIESST effect when it was illuminated at 1000 nm. We also confirmed that the introduction of strong intermolecular interactions, such as π-π stacking, can play an important role in LIESST effect.","subitem_description_type":"Other"}]},"item_16_description_77":{"attribute_name":"URL","attribute_value_mlt":[{"subitem_description":"http://link.springer.com/article/10.1007%2Fs10847-011-9960-3","subitem_description_type":"Other"}]},"item_16_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Springer"}]},"item_16_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1007/s10847-011-9960-3","subitem_relation_type_select":"DOI"}}]},"item_16_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2011 Springer"}]},"item_16_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"09230750","subitem_source_identifier_type":"ISSN"}]},"item_16_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"436","subitem_subject_scheme":"NDC"}]},"item_16_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"807512 bytes"}]},"item_16_text_47":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"雑誌掲載論文"}]},"item_16_text_48":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Journal Article"}]},"item_16_text_49":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_16_text_50":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"01"}]},"item_16_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shimizu, Tetsuya"}],"nameIdentifiers":[{"nameIdentifier":"147052","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Komatsu, Yasuka"}],"nameIdentifiers":[{"nameIdentifier":"147053","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"上畠, 秀允","creatorNameLang":"ja"},{"creatorName":"カミハタ, ヒデノブ","creatorNameLang":"ja-Kana"},{"creatorName":"Kamihata, Hidenobu","creatorNameLang":"en"}],"familyNames":[{"familyName":"上畠","familyNameLang":"ja"},{"familyName":"カミハタ","familyNameLang":"ja-Kana"},{"familyName":"Kamihata","familyNameLang":"en"}],"givenNames":[{"givenName":"秀允","givenNameLang":"ja"},{"givenName":"ヒデノブ","givenNameLang":"ja-Kana"},{"givenName":"Hidenobu","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"147054","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"Lee, Young Hoon","creatorNameLang":"ja"},{"creatorName":"Lee, Young Hoon","creatorNameLang":"en"}],"familyNames":[{"familyName":"Lee","familyNameLang":"ja"},{"familyName":"Lee","familyNameLang":"en"}],"givenNames":[{"givenName":"Young Hoon","givenNameLang":"ja"},{"givenName":"Young Hoon","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"147055","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Fuyuhiro, Akira"}],"nameIdentifiers":[{"nameIdentifier":"147056","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Iijima, Seiichiro"}],"nameIdentifiers":[{"nameIdentifier":"147057","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"速水, 真也","creatorNameLang":"ja"},{"creatorName":"ハヤミ, シンヤ","creatorNameLang":"ja-Kana"},{"creatorName":"Hayami, Shinya","creatorNameLang":"en"}],"familyNames":[{"familyName":"速水","familyNameLang":"ja"},{"familyName":"ハヤミ","familyNameLang":"ja-Kana"},{"familyName":"Hayami","familyNameLang":"en"}],"givenNames":[{"givenName":"真也","givenNameLang":"ja"},{"givenName":"シンヤ","givenNameLang":"ja-Kana"},{"givenName":"Shinya","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"112210","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-02"}],"displaytype":"detail","filename":"J of Incl. Phen. Macr. Chem. 2011 71-3-4-363-369.pdf","filesize":[{"value":"807.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"J of Incl. Phen. Macr. Chem. 2011 71-3-4-363-369.pdf","url":"https://kumadai.repo.nii.ac.jp/record/26749/files/J of Incl. Phen. Macr. Chem. 2011 71-3-4-363-369.pdf"},"version_id":"68ef9474-7f70-4b7d-bd33-adab9262c5de"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Iron(III)","subitem_subject_scheme":"Other"},{"subitem_subject":"Spin-Crossover","subitem_subject_scheme":"Other"},{"subitem_subject":"LIESST","subitem_subject_scheme":"Other"},{"subitem_subject":"Intermolecular Interaction","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Photo-switchable spin-crossover iron(III) compound based on intermolecular interactions","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Photo-switchable spin-crossover iron(III) compound based on intermolecular interactions"}]},"item_type_id":"16","owner":"1","path":["449"],"pubdate":{"attribute_name":"公開日","attribute_value":"2013-01-28"},"publish_date":"2013-01-28","publish_status":"0","recid":"26749","relation_version_is_last":true,"title":["Photo-switchable spin-crossover iron(III) compound based on intermolecular interactions"],"weko_creator_id":"1","weko_shared_id":1},"updated":"2023-09-11T06:35:17.057343+00:00"}