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Formation of 1,2-Dioxan-3-ol Derivatives from Manganese(III)-Based Oxidative Reaction Using Diarylethenes, Diketene, and Ethanol
http://hdl.handle.net/2298/27686
http://hdl.handle.net/2298/276863418e2b3-6d61-4633-a978-ea611572d9ab
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
KT0020_005-009.pdf (247.1 kB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2013-05-16 | |||||
| タイトル | ||||||
| タイトル | Formation of 1,2-Dioxan-3-ol Derivatives from Manganese(III)-Based Oxidative Reaction Using Diarylethenes, Diketene, and Ethanol | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 主題 | Endoperoxides, Aerobic oxidation, Manganese(III) acetate, Diketene, Kinetic control | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | departmental bulletin paper | |||||
| 著者 |
Nguyen, Van-Ha
× Nguyen, Van-Ha× 西野, 宏 |
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| 別言語の著者 |
Nishino, Hiroshi
× Nishino, Hiroshi |
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| 内容記述 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Diketene readily underwent reaction with manganese(III) acetate dihydrate in the presence of ethanol as a nucleophile to produce the enolate complexes A and B, of which subsequent reaction with diarylethenes 1 in air gave three 1,2-dioxan-3-ol products 2, 3, and 4. Major products 2 and 4 were produced by the oxidation of unstable nonconjugated manganese(III)-enolate complex A. The proportion of 2 and 4 depended on the amount of diketene used. The 1,2-dioxan-3-ol 3 derived from the conjugated manganese(III)-enolate complex B was also obtained as a minor product. The reaction pathway for the formation of the endoperoxides 2-4 is discussed. | |||||
| 書誌情報 |
熊本大学極低温装置室ユーザー研究報告書 : 熊大極低温 巻 20, p. 5-9, 発行年 2010-03 |
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| NCID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA12112448 | |||||
| フォーマット | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | application/pdf | |||||
| 形態 | ||||||
| 値 | 247095 bytes | |||||
| 著者版フラグ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| 日本十進分類法 | ||||||
| 主題Scheme | NDC | |||||
| 主題 | 436 | |||||
| 出版者 | ||||||
| 出版者 | 熊本大学 | |||||
| 資源タイプ | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | 論文(Article) | |||||
| 資源タイプ・ローカル | ||||||
| 値 | 紀要論文 | |||||
| 資源タイプ・NII | ||||||
| 値 | Departmental Bulletin Paper | |||||
| 資源タイプ・DCMI | ||||||
| 値 | text | |||||
| 資源タイプ・ローカル表示コード | ||||||
| 値 | 02 | |||||
| コメント | ||||||
| 値 | Cryogenics Report of Kumamoto University | |||||
