{"created":"2023-06-19T09:18:06.960371+00:00","id":30976,"links":{},"metadata":{"_buckets":{"deposit":"4b44738d-b811-44a1-9050-1281c8183833"},"_deposit":{"created_by":1,"id":"30976","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"30976"},"status":"published"},"_oai":{"id":"oai:kumadai.repo.nii.ac.jp:00030976","sets":["448:449"]},"author_link":["146758","143643","143647"],"item_24_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-09","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"450","bibliographicPageStart":"431","bibliographicVolumeNumber":"97","bibliographic_titles":[{"bibliographic_title":"Heterocycles"}]}]},"item_24_creator_3":{"attribute_name":"別言語の著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"井上, 健"}],"nameIdentifiers":[{"nameIdentifier":"143647","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"Nishino, Hiroshi","creatorNameLang":"en"},{"creatorName":"西野, 宏","creatorNameLang":"ja"},{"creatorName":"ニシノ, ヒロシ","creatorNameLang":"ja-Kana"}],"familyNames":[{"familyName":"Nishino","familyNameLang":"en"},{"familyName":"西野","familyNameLang":"ja"},{"familyName":"ニシノ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":"Hiroshi","givenNameLang":"en"},{"givenName":"宏","givenNameLang":"ja"},{"givenName":"ヒロシ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"146758","nameIdentifierScheme":"WEKO"}]}]},"item_24_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf"}]},"item_24_description_46":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"論文"}]},"item_24_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Based on the oxidation of indole with Mn(OAc)3 in the presence of 1,1-diarylethenes affording 3-vinyl-substituted indoles, a similar oxidation using indole-2-carboxylic acids was evaluated in order to effectively introduce the substituent group to the C-3 position of the indolecarboxylic acids. The coupling reaction followed by oxidative cyclization smoothly proceeded at room temperature in an AcOH-HCO2H mixed solvent to give the desired indolelactones in high yields. The reaction details, the structure determination of the products and a brief reaction mechanism are described.","subitem_description_type":"Other"}]},"item_24_description_77":{"attribute_name":"URL","attribute_value_mlt":[{"subitem_description":"https://www.heterocycles.jp/newlibrary/libraries/abst/25555"}]},"item_24_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Japan Institute of Heterocyclic Chemistry"}]},"item_24_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.3987/COM-18-S(T)31","subitem_relation_type_select":"DOI"}}]},"item_24_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"ⓒ2018 The Japan Institute of Heterocyclic Chemistry"}]},"item_24_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03855414","subitem_source_identifier_type":"ISSN"}]},"item_24_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00663739","subitem_source_identifier_type":"NCID"}]},"item_24_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"438","subitem_subject_scheme":"NDC"}]},"item_24_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"1419677 bytes"}]},"item_24_text_47":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"雑誌掲載論文"}]},"item_24_text_48":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Article"}]},"item_24_text_49":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_24_text_50":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"01"}]},"item_24_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Inoue, Takeshi"}],"nameIdentifiers":[{"nameIdentifier":"143643","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"Nishino, Hiroshi","creatorNameLang":"en"},{"creatorName":"西野, 宏","creatorNameLang":"ja"},{"creatorName":"ニシノ, ヒロシ","creatorNameLang":"ja-Kana"}],"familyNames":[{"familyName":"Nishino","familyNameLang":"en"},{"familyName":"西野","familyNameLang":"ja"},{"familyName":"ニシノ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":"Hiroshi","givenNameLang":"en"},{"givenName":"宏","givenNameLang":"ja"},{"givenName":"ヒロシ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"146758","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-03"}],"displaytype":"detail","filename":"Heterocycles2018,97,431-450.pdf","filesize":[{"value":"1.4 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Heterocycles2018,97,431-450.pdf","url":"https://kumadai.repo.nii.ac.jp/record/30976/files/Heterocycles2018,97,431-450.pdf"},"version_id":"73b1450f-a7d6-4039-a59c-198fc7879cd7"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Indolelactones","subitem_subject_scheme":"Other"},{"subitem_subject":"Oxidative substitution","subitem_subject_scheme":"Other"},{"subitem_subject":"Oxidative Cyclization","subitem_subject_scheme":"Other"},{"subitem_subject":"Indole-2-carboxylic acids","subitem_subject_scheme":"Other"},{"subitem_subject":"Manganese(III) acetate","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Facile Synthesis of Indolelactones Using Mn(III)-Based Oxidative Substitution-Cyclization Reaction","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Facile Synthesis of Indolelactones Using Mn(III)-Based Oxidative Substitution-Cyclization Reaction"}]},"item_type_id":"24","owner":"1","path":["449"],"pubdate":{"attribute_name":"公開日","attribute_value":"2019-01-21"},"publish_date":"2019-01-21","publish_status":"0","recid":"30976","relation_version_is_last":true,"title":["Facile Synthesis of Indolelactones Using Mn(III)-Based Oxidative Substitution-Cyclization Reaction"],"weko_creator_id":"1","weko_shared_id":1},"updated":"2023-08-21T01:42:04.323337+00:00"}