@article{oai:kumadai.repo.nii.ac.jp:00030977,
 author = {Nishino, Hiroshi and 西野, 宏 and Huynh, Thanh-Truc and Yamakawa, Hiroyasu and Nguyen, Van-Ha and Nishino, Hiroshi and 西野, 宏},
 issue = {23},
 journal = {ChemistrySelect},
 month = {Jun},
 note = {application/pdf, 論文, The Mn(III)-based oxidation of 1,1-disubstituted ethenes with 2-(2-aryl-2-oxoethyl)malonates, 2-acetyl-4-aryl-4-oxobutanoates, and 3-acetyl-1-arylpentane-1,4-diones was evaluated. The reaction using the malonates mainly gave the 2,3-dihydro-4H-pyran-4,4-dicarboxylates along with γ-lactones. A similar reaction using the acetyloxobutanoates and acetylpentanediones produced the 2,3,3a,6a-tetrahydrofuro[2,3-b]furans and the corresponding dihydropyrans. The cyclization was strongly affected by the nucleophilicity of the carbonyl oxygen in the carbocation intermediate, and the kinetic and thermodynamic controls of the following reaction. The structure determination and the mechanisms are discussed., https://onlinelibrary.wiley.com/doi/abs/10.1002/slct.201801443},
 pages = {6414--6420},
 title = {Mn(III)‐Based Oxidative Cyclization of Alkenes Using Tricarbonyl System},
 volume = {3},
 year = {2018},
 yomi = {ニシノ, ヒロシ and ニシノ, ヒロシ}
}