{"created":"2023-06-19T09:18:07.004216+00:00","id":30977,"links":{},"metadata":{"_buckets":{"deposit":"031ce4cc-0e77-43c3-9a8a-adf71f3b440d"},"_deposit":{"created_by":128,"id":"30977","owners":[128],"pid":{"revision_id":0,"type":"depid","value":"30977"},"status":"published"},"_oai":{"id":"oai:kumadai.repo.nii.ac.jp:00030977","sets":["448:449"]},"author_link":[],"item_24_biblio_info_6":{"attribute_name":"bibliographic_information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-06-19","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"23","bibliographicPageEnd":"6420","bibliographicPageStart":"6414","bibliographicVolumeNumber":"3","bibliographic_titles":[{"bibliographic_title":"ChemistrySelect","bibliographic_titleLang":"en"}]}]},"item_24_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"The Mn(III)-based oxidation of 1,1-disubstituted ethenes with 2-(2-aryl-2-oxoethyl)malonates, 2-acetyl-4-aryl-4-oxobutanoates, and 3-acetyl-1-arylpentane-1,4-diones was evaluated. The reaction using the malonates mainly gave the 2,3-dihydro-4H-pyran-4,4-dicarboxylates along with γ-lactones. A similar reaction using the acetyloxobutanoates and acetylpentanediones produced the 2,3,3a,6a-tetrahydrofuro[2,3-b]furans and the corresponding dihydropyrans. The cyclization was strongly affected by the nucleophilicity of the carbonyl oxygen in the carbocation intermediate, and the kinetic and thermodynamic controls of the following reaction. The structure determination and the mechanisms are discussed.","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_24_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley‐VCH","subitem_publisher_language":"en"}]},"item_24_relation_61":{"attribute_name":"関連","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/slct.201801443","subitem_relation_type_select":"DOI"}}]},"item_24_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"(C)2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim","subitem_rights_language":"en"}]},"item_24_source_id_7":{"attribute_name":"item_24_source_id_7","attribute_value_mlt":[{"subitem_source_identifier":"2365-6549","subitem_source_identifier_type":"PISSN"}]},"item_24_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"438","subitem_subject_scheme":"NDC"}]},"item_24_text_78":{"attribute_name":"コメント","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"This is the peer reviewed version of the following article: [https://onlinelibrary.wiley.com/toc/23656549/3/23], which has been published in final form at [https://doi.org/10.1002/slct.201801443]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."}]},"item_24_version_type_19":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Huynh, Thanh-Truc","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Yamakawa, Hiroyasu","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Nguyen, Van-Ha","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"西野, 宏","creatorNameLang":"ja"},{"creatorName":"ニシノ, ヒロシ","creatorNameLang":"ja-Kana"},{"creatorName":"Nishino, Hiroshi","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2020-03-03"}],"displaytype":"detail","filename":"slct.201801443R1_re-Revised_manuscript.pdf","filesize":[{"value":"418.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"slct.201801443R1_re-Revised_manuscript.pdf","url":"https://kumadai.repo.nii.ac.jp/record/30977/files/slct.201801443R1_re-Revised_manuscript.pdf"},"version_id":"8623de69-6b74-486e-84bc-643a9ce622f9"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"2-Acetyl-4-aryl-4-oxobutanoates","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"3-Acetyl-1-arylpentane-1,4-diones","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"2-(2-Aryl-2-oxoethyl)malonates","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Dihydro-2H-pyrans","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"5-endo-trig","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"6-endo-trig","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Manganese(III) acetate","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Oxidative cyclization","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Tandem cyclization","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"2,3,3a,6a-Tetrahydrofuro[2,3-b]furans","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"item_resource_type","attribute_value_mlt":[{"resourcetype":"article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Mn(III)‐Based Oxidative Cyclization of Alkenes Using Tricarbonyl System","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Mn(III)‐Based Oxidative Cyclization of Alkenes Using Tricarbonyl System","subitem_title_language":"en"}]},"item_type_id":"24","owner":"128","path":["449"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-02-12"},"publish_date":"2020-02-12","publish_status":"0","recid":"30977","relation_version_is_last":true,"title":["Mn(III)‐Based Oxidative Cyclization of Alkenes Using Tricarbonyl System"],"weko_creator_id":"128","weko_shared_id":-1},"updated":"2025-11-07T06:16:16.604365+00:00"}