{"created":"2023-06-19T09:18:07.004216+00:00","id":30977,"links":{},"metadata":{"_buckets":{"deposit":"031ce4cc-0e77-43c3-9a8a-adf71f3b440d"},"_deposit":{"created_by":1,"id":"30977","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"30977"},"status":"published"},"_oai":{"id":"oai:kumadai.repo.nii.ac.jp:00030977","sets":["448:449"]},"author_link":["146758","143649","143651","143650"],"item_24_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-06-19","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"23","bibliographicPageEnd":"6420","bibliographicPageStart":"6414","bibliographicVolumeNumber":"3","bibliographic_titles":[{"bibliographic_title":"ChemistrySelect"}]}]},"item_24_creator_3":{"attribute_name":"別言語の著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"Nishino, Hiroshi","creatorNameLang":"en"},{"creatorName":"西野, 宏","creatorNameLang":"ja"},{"creatorName":"ニシノ, ヒロシ","creatorNameLang":"ja-Kana"}],"familyNames":[{"familyName":"Nishino","familyNameLang":"en"},{"familyName":"西野","familyNameLang":"ja"},{"familyName":"ニシノ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":"Hiroshi","givenNameLang":"en"},{"givenName":"宏","givenNameLang":"ja"},{"givenName":"ヒロシ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"146758","nameIdentifierScheme":"WEKO"}]}]},"item_24_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf"}]},"item_24_description_46":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"論文"}]},"item_24_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"The Mn(III)-based oxidation of 1,1-disubstituted ethenes with 2-(2-aryl-2-oxoethyl)malonates, 2-acetyl-4-aryl-4-oxobutanoates, and 3-acetyl-1-arylpentane-1,4-diones was evaluated. The reaction using the malonates mainly gave the 2,3-dihydro-4H-pyran-4,4-dicarboxylates along with γ-lactones. A similar reaction using the acetyloxobutanoates and acetylpentanediones produced the 2,3,3a,6a-tetrahydrofuro[2,3-b]furans and the corresponding dihydropyrans. The cyclization was strongly affected by the nucleophilicity of the carbonyl oxygen in the carbocation intermediate, and the kinetic and thermodynamic controls of the following reaction. The structure determination and the mechanisms are discussed.","subitem_description_type":"Other"}]},"item_24_description_77":{"attribute_name":"URL","attribute_value_mlt":[{"subitem_description":"https://onlinelibrary.wiley.com/doi/abs/10.1002/slct.201801443"}]},"item_24_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley‐VCH"}]},"item_24_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/slct.201801443","subitem_relation_type_select":"DOI"}}]},"item_24_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim"}]},"item_24_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"23656549","subitem_source_identifier_type":"ISSN"}]},"item_24_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"438","subitem_subject_scheme":"NDC"}]},"item_24_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"418040 bytes"}]},"item_24_text_47":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"雑誌掲載論文"}]},"item_24_text_48":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Article"}]},"item_24_text_49":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_24_text_50":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"01"}]},"item_24_text_78":{"attribute_name":"コメント","attribute_value_mlt":[{"subitem_text_value":"This is the peer reviewed version of the following article: [https://onlinelibrary.wiley.com/toc/23656549/3/23], which has been published in final form at [https://doi.org/10.1002/slct.201801443]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."}]},"item_24_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Huynh, Thanh-Truc"}],"nameIdentifiers":[{"nameIdentifier":"143649","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamakawa, Hiroyasu"}],"nameIdentifiers":[{"nameIdentifier":"143650","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nguyen, Van-Ha"}],"nameIdentifiers":[{"nameIdentifier":"143651","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"Nishino, Hiroshi","creatorNameLang":"en"},{"creatorName":"西野, 宏","creatorNameLang":"ja"},{"creatorName":"ニシノ, ヒロシ","creatorNameLang":"ja-Kana"}],"familyNames":[{"familyName":"Nishino","familyNameLang":"en"},{"familyName":"西野","familyNameLang":"ja"},{"familyName":"ニシノ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":"Hiroshi","givenNameLang":"en"},{"givenName":"宏","givenNameLang":"ja"},{"givenName":"ヒロシ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"146758","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-03"}],"displaytype":"detail","filename":"slct.201801443R1_re-Revised_manuscript.pdf","filesize":[{"value":"418.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"slct.201801443R1_re-Revised_manuscript.pdf","url":"https://kumadai.repo.nii.ac.jp/record/30977/files/slct.201801443R1_re-Revised_manuscript.pdf"},"version_id":"8623de69-6b74-486e-84bc-643a9ce622f9"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"2-Acetyl-4-aryl-4-oxobutanoates","subitem_subject_scheme":"Other"},{"subitem_subject":"3-Acetyl-1-arylpentane-1,4-diones","subitem_subject_scheme":"Other"},{"subitem_subject":"2-(2-Aryl-2-oxoethyl)malonates","subitem_subject_scheme":"Other"},{"subitem_subject":"Dihydro-2H-pyrans","subitem_subject_scheme":"Other"},{"subitem_subject":"5-endo-trig","subitem_subject_scheme":"Other"},{"subitem_subject":"6-endo-trig","subitem_subject_scheme":"Other"},{"subitem_subject":"Manganese(III) acetate","subitem_subject_scheme":"Other"},{"subitem_subject":"Oxidative cyclization","subitem_subject_scheme":"Other"},{"subitem_subject":"Tandem cyclization","subitem_subject_scheme":"Other"},{"subitem_subject":"2,3,3a,6a-Tetrahydrofuro[2,3-b]furans","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Mn(III)‐Based Oxidative Cyclization of Alkenes Using Tricarbonyl System","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Mn(III)‐Based Oxidative Cyclization of Alkenes Using Tricarbonyl System"}]},"item_type_id":"24","owner":"1","path":["449"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-02-12"},"publish_date":"2020-02-12","publish_status":"0","recid":"30977","relation_version_is_last":true,"title":["Mn(III)‐Based Oxidative Cyclization of Alkenes Using Tricarbonyl System"],"weko_creator_id":"1","weko_shared_id":1},"updated":"2023-08-21T01:42:04.559525+00:00"}