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Development of Chiral Dinitrones as Modular Lewis Base Catalysts: Asymmetric Allylation of Aldehydes with Allyltrichlorosilanes
http://hdl.handle.net/2298/18591
http://hdl.handle.net/2298/185913c135c77-b6bb-454a-851e-611b9dd1e9d0
名前 / ファイル | ライセンス | アクション |
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TetAsym21_15_1833-1835.pdf (116.7 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2011-04-21 | |||||
タイトル | ||||||
タイトル | Development of Chiral Dinitrones as Modular Lewis Base Catalysts: Asymmetric Allylation of Aldehydes with Allyltrichlorosilanes | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ | journal article | |||||
著者 |
呉, 英先
× 呉, 英先× Kotani, Shunsuke× Sugiura, Masaharu× 中島, 誠 |
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内容記述 | ||||||
内容記述 | Chiral dinitrones were synthesized by condensation of a C2-symmetrical chiral dihydroxylamine with various aldehydes. The electronic and steric properties of the dinitrones can be modified by changing the aldehyde component. The activity of dinitrones as Lewis base catalysts was examined for the asymmetric allylation of aldehydes with allyltrichlorosilanes. Using DMPU as an additive in chloroform, the reaction proceeded at room temperature to afford allylated products in good yields and good enantioselectivities. | |||||
書誌情報 |
Tetrahedron Asymmetry 巻 21, 号 15, p. 1833-1835, 発行年 2010-08-04 |
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DOI | ||||||
関連タイプ | isVersionOf | |||||
関連識別子 | https://doi.org/10.1016/j.tetasy.2010.05.048 | |||||
権利 | ||||||
権利情報 | © 2010 Elsevier Ltd. | |||||
情報源(ISSN) | ||||||
関連名称 | 09574166 | |||||
フォーマット | ||||||
内容記述 | application/pdf | |||||
形態 | ||||||
116730 bytes | ||||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
日本十進分類法 | ||||||
主題 | 499.3 | |||||
出版者 | ||||||
出版者 | Elsevier | |||||
資源タイプ | ||||||
内容記述 | 論文(Article) | |||||
資源タイプ・ローカル | ||||||
雑誌掲載論文 | ||||||
資源タイプ・NII | ||||||
Journal Article | ||||||
資源タイプ・DCMI | ||||||
text | ||||||
資源タイプ・ローカル表示コード | ||||||
01 |