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Mn(III)-initiated facile oxygenation of heterocyclic 1,3-dicarbonyl compounds
http://hdl.handle.net/2298/25261
http://hdl.handle.net/2298/252611dfb7e92-2819-4457-bec3-c12bd5fdd457
名前 / ファイル | ライセンス | アクション |
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Molecules-,2011,16,9562-9581-full version.pdf (708.4 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2012-07-31 | |||||
タイトル | ||||||
タイトル | Mn(III)-initiated facile oxygenation of heterocyclic 1,3-dicarbonyl compounds | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | hydroperoxides, peroxy radicals, aerobic oxidation, redox, 2-hydroxy-1,3- dicarbonyl compounds | |||||
資源タイプ | ||||||
資源タイプ | journal article | |||||
著者 |
Rahman, Taifur
× Rahman, Taifur× Haque, Md. Aminul× Igarashi, Hikaru× Nishino, Hiroshi |
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別言語の著者 |
五十嵐, 光
× 五十嵐, 光× 西野, 宏 |
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内容記述 | ||||||
内容記述 | The Mn(III)-initiated aerobic oxidation of heterocyclic 1,3-dicarbonyl compounds, such as 4-alkyl-1,2-diphenylpyrazolidine-3,5-diones, 1,3-dialkylpyrrolidine- 2,4-diones, 3-alkyl-1,5-dimethylbarbituric acids, and 3-butyl-4-hydroxy-2-quinolinone gave excellent to good yields of the corresponding hydroperoxides, which were gradually degraded by exposure to the metal initiator after the reaction to afford the corresponding alcohols. The synthesis of 30 heterocyclic 1,3-dicarbonyl compounds, the corresponding hydroperoxides and the 10 alcohols, their characterization, and the limitations of the procedure are described. In addition, the mechanism of the hydroperoxidation and the redox decomposition of the hydroperoxides are discussed. |
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書誌情報 |
Molecules 巻 16, 号 11, p. 9562-9581, 発行年 2011-11 |
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ISSN | ||||||
収録物識別子 | 14203049 | |||||
PubMed番号 | ||||||
関連タイプ | isIdenticalTo | |||||
関連識別子 | 22089863 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
関連識別子 | 10.3390/molecules16119562 | |||||
フォーマット | ||||||
内容記述 | application/pdf | |||||
フォーマット | ||||||
内容記述 | application/pdf | |||||
形態 | ||||||
708401 bytes | ||||||
形態 | ||||||
58277 bytes | ||||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
日本十進分類法 | ||||||
主題 | 430 | |||||
出版者 | ||||||
出版者 | Molecular Diversity Preservation International | |||||
資源タイプ | ||||||
内容記述 | 論文(Article) | |||||
資源タイプ・ローカル | ||||||
雑誌掲載論文 | ||||||
資源タイプ・NII | ||||||
Journal Article | ||||||
資源タイプ・DCMI | ||||||
text | ||||||
資源タイプ・ローカル表示コード | ||||||
01 | ||||||
URL | ||||||
内容記述 | http://www.mdpi.com/1420-3049/16/11/9562 |