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A Comparative Study of the Viscosity of Ion Conducting Polymers based on the Bond Strength-Coordination Number Fluctuation Model and Other Models
http://hdl.handle.net/2298/33364
http://hdl.handle.net/2298/33364b85a41fb-f981-4688-b8b3-a931f207698b
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
J_Solid_State_Electrochem_16_1883-1887.pdf (1.3 MB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2015-10-27 | |||||
| タイトル | ||||||
| タイトル | A Comparative Study of the Viscosity of Ion Conducting Polymers based on the Bond Strength-Coordination Number Fluctuation Model and Other Models | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 主題 | Bond Strength-Coordination Number Fluctuation Model, Viscosity, Ion Conducting Polymer, Vogel-Fulcher-Tamman Equation, Williams-Landel-Ferry Equation | |||||
| 資源タイプ | ||||||
| 資源タイプ | journal article | |||||
| 著者 |
Sahara
× Sahara× Aniya, Masaru |
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| 別言語の著者 |
サハラ,
× サハラ,× 安仁屋, 勝 |
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| 内容記述 | ||||||
| 内容記述 | According to the Bond Strength-Coordination Number Fluctuation (BSCNF) model of the viscosity proposed some years ago by one of the authors, the viscosity is controlled by the relaxation of structural units that form the melt, and is described in terms of the average bond strength, coordination number and their fluctuations of the structural units. In the present paper, a comparative study of the viscosity of ion conducting polymeric system is presented. The analysis has been done though the BSCNF model and other models widely used in the literature such as Vogel-Fulcher-Tamman (VFT) and Williams-Landel-Ferry (WLF) equations. The result reveals that the three models describe well the temperature dependence of the viscosity reported experimentally. As a gross trend, the fragility of the polymeric system in consideration increases with the increase in the concentration of salts. Based on the analysis with the BSCNF model, such a behavior has been interptreted to arise from the disruption of the network that results by the addition of salts. Tha comparative study also reveals that the BSCNF model could provide a physical interpretation to the empirical parameters used in other models. | |||||
| 書誌情報 |
Journal of Solid State Electrochemistry 巻 16, 号 5, p. 1883-1887, 発行年 2012-05-01 |
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| ISSN | ||||||
| 収録物識別子 | 14328488 | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 関連識別子 | 10.1007/s10008-012-1686-7 | |||||
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| 内容記述タイプ | Other | |||||
| 内容記述 | application/pdf | |||||
| 形態 | ||||||
| 1280963 bytes | ||||||
| 著者版フラグ | ||||||
| 出版タイプ | AM | |||||
| 日本十進分類法 | ||||||
| 主題Scheme | NDC | |||||
| 主題 | 420 | |||||
| 出版者 | ||||||
| 出版者 | Springer Verlaq | |||||
| 資源タイプ | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | 論文(Article) | |||||
| 資源タイプ・ローカル | ||||||
| 雑誌掲載論文 | ||||||
| 資源タイプ・NII | ||||||
| Journal Article | ||||||
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| text | ||||||
| 資源タイプ・ローカル表示コード | ||||||
| 01 | ||||||
| URL | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | http://link.springer.com/article/10.1007%2Fs10008-012-1686-7 | |||||
| コメント | ||||||
| The final publication is available at Springer via http://dx.doi.org/10.1007/s10008-012-1686-7. | ||||||
| コメント | ||||||
| 【著者所属】熊本大学大学院自然科学研究科 理学専攻 | ||||||
