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Facile Synthesis of Indolelactones Using Mn(III)-Based Oxidative Substitution-Cyclization Reaction
http://hdl.handle.net/2298/41403
http://hdl.handle.net/2298/41403734aff21-a563-4cc7-a271-2064fc4e6ed1
名前 / ファイル | ライセンス | アクション |
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Heterocycles2018,97,431-450.pdf (1.4 MB)
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Item type | 一般雑誌記事 / Article(1) | |||||
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公開日 | 2019-01-21 | |||||
タイトル | ||||||
タイトル | Facile Synthesis of Indolelactones Using Mn(III)-Based Oxidative Substitution-Cyclization Reaction | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | Indolelactones, Oxidative substitution, Oxidative Cyclization, Indole-2-carboxylic acids, Manganese(III) acetate | |||||
資源タイプ | ||||||
資源タイプ | article | |||||
著者 |
Inoue, Takeshi
× Inoue, Takeshi× 西野, 宏 |
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別言語の著者 |
井上, 健
× 井上, 健× 西野, 宏 |
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内容記述 | ||||||
内容記述 | Based on the oxidation of indole with Mn(OAc)3 in the presence of 1,1-diarylethenes affording 3-vinyl-substituted indoles, a similar oxidation using indole-2-carboxylic acids was evaluated in order to effectively introduce the substituent group to the C-3 position of the indolecarboxylic acids. The coupling reaction followed by oxidative cyclization smoothly proceeded at room temperature in an AcOH-HCO2H mixed solvent to give the desired indolelactones in high yields. The reaction details, the structure determination of the products and a brief reaction mechanism are described. | |||||
書誌情報 |
Heterocycles 巻 97, 号 1, p. 431-450, 発行日 2018-09 |
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ISSN | ||||||
収録物識別子 | 03855414 | |||||
書誌レコードID | ||||||
収録物識別子 | AA00663739 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
関連識別子 | https://doi.org/10.3987/COM-18-S(T)31 | |||||
権利 | ||||||
権利情報 | ⓒ2018 The Japan Institute of Heterocyclic Chemistry | |||||
フォーマット | ||||||
内容記述 | application/pdf | |||||
形態 | ||||||
1419677 bytes | ||||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
日本十進分類法 | ||||||
主題 | 438 | |||||
出版者 | ||||||
出版者 | The Japan Institute of Heterocyclic Chemistry | |||||
資源タイプ | ||||||
内容記述 | 論文 | |||||
資源タイプ・ローカル | ||||||
雑誌掲載論文 | ||||||
資源タイプ・NII | ||||||
Article | ||||||
資源タイプ・DCMI | ||||||
text | ||||||
資源タイプ・ローカル表示コード | ||||||
01 | ||||||
URL | ||||||
内容記述 | https://www.heterocycles.jp/newlibrary/libraries/abst/25555 |