| Item type |
一般雑誌記事 / Article(1) |
| 公開日 |
2020-02-12 |
| タイトル |
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タイトル |
Mn(III)‐Based Oxidative Cyclization of Alkenes Using Tricarbonyl System |
|
言語 |
en |
| 言語 |
|
|
言語 |
eng |
| キーワード |
|
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主題 |
2-Acetyl-4-aryl-4-oxobutanoates, 3-Acetyl-1-arylpentane-1,4-diones, 2-(2-Aryl-2-oxoethyl)malonates, Dihydro-2H-pyrans, 5-endo-trig, 6-endo-trig, Manganese(III) acetate, Oxidative cyclization, Tandem cyclization, 2,3,3a,6a-Tetrahydrofuro[2,3-b]furans |
| 資源タイプ |
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資源タイプ |
article |
| アクセス権 |
|
|
アクセス権 |
open access |
| 著者 |
Huynh, Thanh-Truc
Yamakawa, Hiroyasu
Nguyen, Van-Ha
西野, 宏
|
| 内容記述 |
|
|
内容記述タイプ |
Other |
|
内容記述 |
The Mn(III)-based oxidation of 1,1-disubstituted ethenes with 2-(2-aryl-2-oxoethyl)malonates, 2-acetyl-4-aryl-4-oxobutanoates, and 3-acetyl-1-arylpentane-1,4-diones was evaluated. The reaction using the malonates mainly gave the 2,3-dihydro-4H-pyran-4,4-dicarboxylates along with γ-lactones. A similar reaction using the acetyloxobutanoates and acetylpentanediones produced the 2,3,3a,6a-tetrahydrofuro[2,3-b]furans and the corresponding dihydropyrans. The cyclization was strongly affected by the nucleophilicity of the carbonyl oxygen in the carbocation intermediate, and the kinetic and thermodynamic controls of the following reaction. The structure determination and the mechanisms are discussed. |
| bibliographic_information |
en : ChemistrySelect
巻 3,
号 23,
p. 6414-6420,
発行日 2018-06-19
|
| item_24_source_id_7 |
|
|
収録物識別子 |
2365-6549 |
| 権利 |
|
|
言語 |
en |
|
権利情報 |
(C)2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim |
| 出版タイプ |
|
|
出版タイプ |
AM |
| 日本十進分類法 |
|
|
主題Scheme |
NDC |
|
主題 |
438 |
| 出版者 |
|
|
出版者 |
Wiley‐VCH |
|
言語 |
en |
| 関連 |
|
|
関連タイプ |
isVersionOf |
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
10.1002/slct.201801443 |
| コメント |
|
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|
This is the peer reviewed version of the following article: [https://onlinelibrary.wiley.com/toc/23656549/3/23], which has been published in final form at [https://doi.org/10.1002/slct.201801443]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. |
slct.201801443R1_re-Revised_manuscript.pdf (418.0 kB)
